Processing of monolayer materials via interfacial reactions
Abstract
A method of forming and processing of graphene is disclosed based on exposure and selective intercalation of the partially graphene-covered metal substrate with atomic or molecular intercalation species such as oxygen (O.sub.2) and nitrogen oxide (NO.sub.2). The process of intercalation lifts the strong metal-carbon coupling and restores the characteristic Dirac behavior of isolated monolayer graphene. The interface of graphene with metals or metal-decorated substrates also provides for controlled chemical reactions based on novel functionality of the confined space between a metal surface and a graphene sheet.
- Inventors:
- Issue Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1132268
- Patent Number(s):
- 8728433
- Application Number:
- 13/468,592
- Assignee:
- Brookhaven Science Associates, LLC (Upton, NY)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC02-98CH10886
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2012 May 10
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Sutter, Peter Werner, and Sutter, Eli Anguelova. Processing of monolayer materials via interfacial reactions. United States: N. p., 2014.
Web.
Sutter, Peter Werner, & Sutter, Eli Anguelova. Processing of monolayer materials via interfacial reactions. United States.
Sutter, Peter Werner, and Sutter, Eli Anguelova. Tue .
"Processing of monolayer materials via interfacial reactions". United States. https://www.osti.gov/servlets/purl/1132268.
@article{osti_1132268,
title = {Processing of monolayer materials via interfacial reactions},
author = {Sutter, Peter Werner and Sutter, Eli Anguelova},
abstractNote = {A method of forming and processing of graphene is disclosed based on exposure and selective intercalation of the partially graphene-covered metal substrate with atomic or molecular intercalation species such as oxygen (O.sub.2) and nitrogen oxide (NO.sub.2). The process of intercalation lifts the strong metal-carbon coupling and restores the characteristic Dirac behavior of isolated monolayer graphene. The interface of graphene with metals or metal-decorated substrates also provides for controlled chemical reactions based on novel functionality of the confined space between a metal surface and a graphene sheet.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 20 00:00:00 EDT 2014},
month = {Tue May 20 00:00:00 EDT 2014}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Monolayer and/or Few-Layer Graphene On Metal or Metal-Coated Substrates
patent-application, October 2010
- Sutter, Peter Werner; Sutter, Eli Anguelova
- US Patent Application 12/753281; 20100255984
Intercalation compounds of graphite
journal, January 2002
- Dresselhaus, M. S.; Dresselhaus, G.
- Advances in Physics, Vol. 51, Issue 1
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
Graphene: Exploring carbon flatland
journal, August 2007
- Bodenmann, Andrey K.; MacDonald, Allan H.
- Physics Today, Vol. 60, Issue 8
Ultra-thin epitaxial films of graphite and hexagonal boron nitride on solid surfaces
journal, January 1997
- Oshima, Chuhei; Nagashima, Ayato
- Journal of Physics: Condensed Matter, Vol. 9, Issue 1
Epitaxial graphene on ruthenium
journal, April 2008
- Sutter, Peter W.; Flege, Jan-Ingo; Sutter, Eli A.
- Nature Materials, Vol. 7, Issue 5, p. 406-411
Growth Mechanism of Graphene on Ru(0001) and O 2 Adsorption on the Graphene/Ru(0001) Surface
journal, April 2009
- Zhang, Hui; Fu, Qiang; Cui, Yi
- The Journal of Physical Chemistry C, Vol. 113, Issue 19
Quasi-Free-Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation
journal, December 2009
- Riedl, C.; Coletti, C.; Iwasaki, T.
- Physical Review Letters, Vol. 103, Issue 24
Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation
journal, June 2010
- Sutter, Peter; Sadowski, Jerzy T.; Sutter, Eli A.
- Journal of the American Chemical Society, Vol. 132, Issue 23
Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics
journal, December 2004
- Berger, Claire; Song, Zhimin; Li, Tianbo
- The Journal of Physical Chemistry B, Vol. 108, Issue 52, p. 19912-19916
Electronic states of the pristine and alkali-metal-intercalated monolayer graphite/Ni(111) systems
journal, December 1994
- Nagashima, A.; Tejima, N.; Oshima, C.
- Physical Review B, Vol. 50, Issue 23
Graphene growth on polycrystalline Ru thin films
journal, September 2009
- Sutter, E.; Albrecht, P.; Sutter, P.
- Applied Physics Letters, Vol. 95, Issue 13
Monolayer graphene as ultimate chemical passivation layer for arbitrarily shaped metal surfaces
journal, December 2010
- Sutter, Eli; Albrecht, Peter; Camino, Fernando E.
- Carbon, Vol. 48, Issue 15, p. 4414-4420
Graphene growth on epitaxial Ru thin films on sapphire
journal, November 2010
- Sutter, P. W.; Albrecht, P. M.; Sutter, E. A.
- Applied Physics Letters, Vol. 97, Issue 21
Electronic and Magnetic Properties of Quasifreestanding Graphene on Ni
journal, October 2008
- Varykhalov, A.; Sánchez-Barriga, J.; Shikin, A. M.
- Physical Review Letters, Vol. 101, Issue 15