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Title: Ruthenium or osmium complexes and their uses as catalysts for water oxidation

Abstract

The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
The University of North Carolina at Chapel Hill (Chapel Hill, NC)
Sponsoring Org.:
USDOE
OSTI Identifier:
1092765
Patent Number(s):
8524903
Application Number:
12/862,538
Assignee:
The University of North Carolina at Chapel Hill (Chapel Hill, NC)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
FG02-06ER15788; SC0001011
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Corbea, Javier Jesus Concepcion, Chen, Zuofeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, and Meyer, Thomas J. Ruthenium or osmium complexes and their uses as catalysts for water oxidation. United States: N. p., 2013. Web.
Corbea, Javier Jesus Concepcion, Chen, Zuofeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, & Meyer, Thomas J. Ruthenium or osmium complexes and their uses as catalysts for water oxidation. United States.
Corbea, Javier Jesus Concepcion, Chen, Zuofeng, Jurss, Jonah Wesley, Templeton, Joseph L., Hoertz, Paul, and Meyer, Thomas J. Tue . "Ruthenium or osmium complexes and their uses as catalysts for water oxidation". United States. https://www.osti.gov/servlets/purl/1092765.
@article{osti_1092765,
title = {Ruthenium or osmium complexes and their uses as catalysts for water oxidation},
author = {Corbea, Javier Jesus Concepcion and Chen, Zuofeng and Jurss, Jonah Wesley and Templeton, Joseph L. and Hoertz, Paul and Meyer, Thomas J.},
abstractNote = {The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 03 00:00:00 EDT 2013},
month = {Tue Sep 03 00:00:00 EDT 2013}
}

Works referenced in this record:

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
journal, February 2010


Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010


Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010

  • Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
  • Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
  • https://doi.org/10.1021/ja904906v

Single-Site, Catalytic Water Oxidation on Oxide Surfaces
journal, November 2009

  • Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W.
  • Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581
  • https://doi.org/10.1021/ja906391w