Solid solution lithium alloy cermet anodes
Abstract
A metal-ceramic composite ("cermet") has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California, Oakland, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1087904
- Patent Number(s):
- 8480922
- Application Number:
- 12/665,004
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- AC02-05CH11231
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Richardson, Thomas J. Solid solution lithium alloy cermet anodes. United States: N. p., 2013.
Web.
Richardson, Thomas J. Solid solution lithium alloy cermet anodes. United States.
Richardson, Thomas J. Tue .
"Solid solution lithium alloy cermet anodes". United States. https://www.osti.gov/servlets/purl/1087904.
@article{osti_1087904,
title = {Solid solution lithium alloy cermet anodes},
author = {Richardson, Thomas J.},
abstractNote = {A metal-ceramic composite ("cermet") has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 09 00:00:00 EDT 2013},
month = {Tue Jul 09 00:00:00 EDT 2013}
}
Works referenced in this record:
Solid state thin film battery having a high temperature lithium alloy anode
patent, January 1998
- Hobson, David
- US Patent Document 5,705,293
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Solid State Battery and Method of Making the Same
patent, July 1975
- Mead, Ralph T.
- US Patent Document 3895962
A sealed optical cell for the study of lithium-electrode|electrolyte interfaces
journal, March 2003
- Howlett, P. C.; MacFarlane, D. R.; Hollenkamp, A. F.
- Journal of Power Sources, Vol. 114, Issue 2
Solid solution lithium alloy cermet anodes
journal, December 2007
- Richardson, Thomas J.; Chen, Guoying
- Journal of Power Sources, Vol. 174, Issue 2
Electrodes for electrochemical devices
patent, September 1994
- Hope, Stephen F.; Kejha, Joseph B.
- US Patent Document 5,350,647
Electrochromic devices based on lithium insertion
patent, May 2006
- Richardson, Thomas
- US Patent Document 7,042,615
Process for obtaining lithium-based thin sheets and its application to the production of negative plates for accumulators
patent, April 1992
- Raynaud, Guy-Michel; Regazzoni, Gilles; Nussbaum, Gilles
- US Patent Document 5,102,475
Lithium secondary battery and cathode composition therefor
patent, February 2001
- Watanabe, Isao; Horiuchi, Hiroshi; Yoshida, Kensuke
- US Patent Document 6,187,477
Lithium Secondary Battery
patent-application, February 2002
- Nakura, Kensuke
- US Patent Application 09/893,895; 2002/0015890 Al