Method and system for hydrogen evolution and storage

Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

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Title: Method and system for hydrogen evolution and storage

Abstract

A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

Inventors:: Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

Issue Date:: Tue Dec 11 00:00:00 EST 2012

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1082452

Patent Number(s):: 8329140

Application Number:: 12/283,462

Assignee:: Los Alamos National Security, LLC (Los Alamos, NM)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D235/06 - with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
C07D235/18 - with aryl radicals directly attached in position 2

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DOE Contract Number:: AC52-06NA25396

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 08 HYDROGEN

Citation Formats


                    Thorn, David L., Tumas, William, Hay, P. Jeffrey, Schwarz, Daniel E., and Cameron, Thomas M. Method and system for hydrogen evolution and storage.  United States: N. p., 2012. 
        Web.

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                    Thorn, David L., Tumas, William, Hay, P. Jeffrey, Schwarz, Daniel E., & Cameron, Thomas M. Method and system for hydrogen evolution and storage.  United States.

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                    Thorn, David L., Tumas, William, Hay, P. Jeffrey, Schwarz, Daniel E., and Cameron, Thomas M. Tue .  
        "Method and system for hydrogen evolution and storage".  United States.  https://www.osti.gov/servlets/purl/1082452.

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@article{osti_1082452,

  title        = {Method and system for hydrogen evolution and storage},

  author       = {Thorn, David L. and Tumas, William and Hay, P. Jeffrey and Schwarz, Daniel E. and Cameron, Thomas M.},

  abstractNote = {A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Dec 11 00:00:00 EST 2012},

  month        = {Tue Dec 11 00:00:00 EST 2012}

}

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Works referenced in this record:

Catalysed low temperature H2 release from nitrogen heterocycles
journal, January 2006

Moores, Audrey; Poyatos, Macarena; Luo, Yi
New Journal of Chemistry, Vol. 30, Issue 11
https://doi.org/10.1039/b608914c

Formal transfers of hydride from carbon–hydrogen bonds. Attempted generation of H ₂ by intramolecular protonolyses of the activated carbon–hydrogen bonds of dihydrobenzimidazoles
journal, May 1996

Brunet, Philippe; Wuest, James D.
Canadian Journal of Chemistry, Vol. 74, Issue 5
https://doi.org/10.1139/v96-074

Formal Transfers of Hydride from Carbon−Hydrogen Bonds. Generation of H ₂ from Orthoformamides Designed To Undergo Intramolecular Protonolyses of Activated Carbon−Hydrogen Bonds
journal, January 1996

Brunet, Philippe; Wuest, James D.
The Journal of Organic Chemistry, Vol. 61, Issue 6
https://doi.org/10.1021/jo951636p

Triruthenium dodecacarbonyl/triphenylphosphine catalyzed dehydrogenation of primary and secondary alcohols
journal, January 2004

Meijer, R. H.; Ligthart, G. B. W. L.; Meuldijk, J.
Tetrahedron, Vol. 60, Issue 5
https://doi.org/10.1016/j.tet.2003.11.082

Use of carbon dioxide in energy storage
journal, September 1978

Williams, Richard; Crandall, Richard S.; Bloom, Allen
Applied Physics Letters, Vol. 33, Issue 5
https://doi.org/10.1063/1.90403

Highly sustainable catalytic dehydrogenation of alcohols with evolution of hydrogen gas
journal, February 2003

Ligthart, G. B. W. L.; Meijer, R. H.; Donners, M. P. J.
Tetrahedron Letters, Vol. 44, Issue 7
https://doi.org/10.1016/S0040-4039(02)02842-3

Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle
journal, November 2003

Hodoshima, S.
International Journal of Hydrogen Energy, Vol. 28, Issue 11
https://doi.org/10.1016/S0360-3199(02)00250-1

The conversion of polysaccharides to hydrogen gas. Part II: The catalytic decomposition of formaldehyde in the aqueous phase
journal, January 1988

Hill, S. P.; Winterbottom, J. M.
Journal of Chemical Technology & Biotechnology, Vol. 41, Issue 2
https://doi.org/10.1002/jctb.280410206

Thermochemical alkane dehydrogenation catalyzed in solution without the use of a hydrogen acceptor
journal, January 1997

Xu, Wei-wei; Rosini, Glen P.; Krogh-Jespersen, Karsten
Chemical Communications, Issue 23
https://doi.org/10.1039/a705105k

The conversion of polysaccharides to hydrogen gas. Part III
journal, January 1988

Hill, S. P.; Winterbottom, J. M.
Journal of Chemical Technology & Biotechnology, Vol. 41, Issue 3
https://doi.org/10.1002/jctb.280410303

Dehydrogenation of alcohols and hydrogenation of aldehydes using homogeneous ruthenium catalysts
journal, April 1982

Jung, C. W.; Garrou, P. E.
Organometallics, Vol. 1, Issue 4
https://doi.org/10.1021/om00064a016

The conversion of polysaccharides to hydrogen gas. Part I: The palladium catalysed decomposition of formic acid/sodium formate solutions
journal, January 1988

Hill, S. P.; Winterbottom, J. M.
Journal of Chemical Technology & Biotechnology, Vol. 41, Issue 2
https://doi.org/10.1002/jctb.280410205

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Similar Records

Title: Method and system for hydrogen evolution and storage

Abstract

Citation Formats

Catalysed low temperature H2 release from nitrogen heterocycles journal, January 2006

Formal transfers of hydride from carbon–hydrogen bonds. Attempted generation of H 2 by intramolecular protonolyses of the activated carbon–hydrogen bonds of dihydrobenzimidazoles journal, May 1996

Formal Transfers of Hydride from Carbon−Hydrogen Bonds. Generation of H 2 from Orthoformamides Designed To Undergo Intramolecular Protonolyses of Activated Carbon−Hydrogen Bonds journal, January 1996

Triruthenium dodecacarbonyl/triphenylphosphine catalyzed dehydrogenation of primary and secondary alcohols journal, January 2004

Use of carbon dioxide in energy storage journal, September 1978

Highly sustainable catalytic dehydrogenation of alcohols with evolution of hydrogen gas journal, February 2003

Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle journal, November 2003

The conversion of polysaccharides to hydrogen gas. Part II: The catalytic decomposition of formaldehyde in the aqueous phase journal, January 1988

Thermochemical alkane dehydrogenation catalyzed in solution without the use of a hydrogen acceptor journal, January 1997

The conversion of polysaccharides to hydrogen gas. Part III journal, January 1988

Dehydrogenation of alcohols and hydrogenation of aldehydes using homogeneous ruthenium catalysts journal, April 1982

The conversion of polysaccharides to hydrogen gas. Part I: The palladium catalysed decomposition of formic acid/sodium formate solutions journal, January 1988

Catalysed low temperature H2 release from nitrogen heterocycles
journal, January 2006

Formal transfers of hydride from carbon–hydrogen bonds. Attempted generation of H ₂ by intramolecular protonolyses of the activated carbon–hydrogen bonds of dihydrobenzimidazoles
journal, May 1996

Formal Transfers of Hydride from Carbon−Hydrogen Bonds. Generation of H ₂ from Orthoformamides Designed To Undergo Intramolecular Protonolyses of Activated Carbon−Hydrogen Bonds
journal, January 1996

Triruthenium dodecacarbonyl/triphenylphosphine catalyzed dehydrogenation of primary and secondary alcohols
journal, January 2004

Use of carbon dioxide in energy storage
journal, September 1978

Highly sustainable catalytic dehydrogenation of alcohols with evolution of hydrogen gas
journal, February 2003

Catalytic decalin dehydrogenation/naphthalene hydrogenation pair as a hydrogen source for fuel-cell vehicle
journal, November 2003

The conversion of polysaccharides to hydrogen gas. Part II: The catalytic decomposition of formaldehyde in the aqueous phase
journal, January 1988

Thermochemical alkane dehydrogenation catalyzed in solution without the use of a hydrogen acceptor
journal, January 1997

The conversion of polysaccharides to hydrogen gas. Part III
journal, January 1988

Dehydrogenation of alcohols and hydrogenation of aldehydes using homogeneous ruthenium catalysts
journal, April 1982

The conversion of polysaccharides to hydrogen gas. Part I: The palladium catalysed decomposition of formic acid/sodium formate solutions
journal, January 1988