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Title: Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation

Abstract

Methods of oxidative dehydrogenation are described. Surprisingly, Pd and Au alloys of Pt have been discovered to be superior for oxidative dehydrogenation in microchannels. Methods of forming these catalysts via an electroless plating methodology are also described. An apparatus design that minimizes heat transfer to the apparatus' exterior is also described.

Inventors:
 [1];  [2];  [3];  [4];  [5];  [6];  [5];  [7];  [8];  [3]
  1. Dublin, OH
  2. Columbus, OH
  3. Galloway, OH
  4. Solon, OH
  5. New Albany, OH
  6. Delaware, OH
  7. Lewis Center, OH
  8. Westerville, OH
Issue Date:
Research Org.:
Velocys (Plain City, OH)
Sponsoring Org.:
USDOE
OSTI Identifier:
1025531
Patent Number(s):
7999144
Application Number:
11/469,847
Assignee:
Velocys (Plain City, OH)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
FC36-04GO14154
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Tonkovich, Anna Lee, Yang, Bin, Perry, Steven T, Mazanec, Terry, Arora, Ravi, Daly, Francis P, Long, Richard, Yuschak, Thomas D, Neagle, Paul W, and Glass, Amanda. Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation. United States: N. p., 2011. Web.
Tonkovich, Anna Lee, Yang, Bin, Perry, Steven T, Mazanec, Terry, Arora, Ravi, Daly, Francis P, Long, Richard, Yuschak, Thomas D, Neagle, Paul W, & Glass, Amanda. Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation. United States.
Tonkovich, Anna Lee, Yang, Bin, Perry, Steven T, Mazanec, Terry, Arora, Ravi, Daly, Francis P, Long, Richard, Yuschak, Thomas D, Neagle, Paul W, and Glass, Amanda. Tue . "Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation". United States. https://www.osti.gov/servlets/purl/1025531.
@article{osti_1025531,
title = {Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation},
author = {Tonkovich, Anna Lee and Yang, Bin and Perry, Steven T and Mazanec, Terry and Arora, Ravi and Daly, Francis P and Long, Richard and Yuschak, Thomas D and Neagle, Paul W and Glass, Amanda},
abstractNote = {Methods of oxidative dehydrogenation are described. Surprisingly, Pd and Au alloys of Pt have been discovered to be superior for oxidative dehydrogenation in microchannels. Methods of forming these catalysts via an electroless plating methodology are also described. An apparatus design that minimizes heat transfer to the apparatus' exterior is also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 16 00:00:00 EDT 2011},
month = {Tue Aug 16 00:00:00 EDT 2011}
}

Works referenced in this record:

Dehydrogenation and oxydehydrogenation of paraffins to olefins
journal, November 2001


Synthesis of ethylene oxide in a microreaction system
book, January 2000


Novel Membrane Reactor with Filamentous Catalytic Bed for Propane Dehydrogenation
journal, November 2001


Miniaturization of screening devices for the combinatorial development of heterogeneous catalysts
journal, June 2001


Production of olefins via oxidative dehydrogenation of light paraffins at short contact times
journal, January 2001