3582 K
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TitleResearch in Chemical Kinetics. Annual Report, 1993
Author(s)Rowland, F. S.
Publication Date1993
Report NumberDOE/ER/13469--T9
Unique IdentifierACC0437
Other NumbersOSTI ID: 656622; Legacy ID: DE98006356
Research OrgUniversity of California, Department of Chemistry, Irvine, CA (United States)
Contract NoFG03-86ER13469
Sponsoring OrgU.S. Department of Energy (DOE) Office of Energy Research (ER), Washington, DC (United States)
Subject40 Chemistry ;54 Environmental Sciences; Progress Report; Chemical Reaction Kinetics; Atmospheric Chemistry; Chlorine; Fluorinated Aliphatic Hydrocarbons; Organometallic Compounds; Refrigerants; Carbon Oxysulfide; Ethane; Propane; Carbon 14; Chlorine 38; Experimental Data
Related Web PagesF. Sherwood Rowland, Chlorofluorocarbons [CFCs], and the Thinning of the Ozone Layer
AbstractProgress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}.
3582 K
80 pp.
 
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