80 pp.
80 pp.
| 3582 K 80 pp. | |
| View Document | ||
| Title | Research in Chemical Kinetics. Annual Report, 1993 | |
| Author(s) | Rowland, F. S. | |
| Publication Date | 1993 | |
| Report Number | DOE/ER/13469--T9 | |
| Unique Identifier | ACC0437 | |
| Other Numbers | OSTI ID: 656622; Legacy ID: DE98006356 | |
| Research Org | University of California, Department of Chemistry, Irvine, CA (United States) | |
| Contract No | FG03-86ER13469 | |
| Sponsoring Org | U.S. Department of Energy (DOE) Office of Energy Research (ER), Washington, DC (United States) | |
| Subject | 40 Chemistry ;54 Environmental Sciences; Progress Report; Chemical Reaction Kinetics; Atmospheric Chemistry; Chlorine; Fluorinated Aliphatic Hydrocarbons; Organometallic Compounds; Refrigerants; Carbon Oxysulfide; Ethane; Propane; Carbon 14; Chlorine 38; Experimental Data | |
| Related Web Pages | F. Sherwood Rowland, Chlorofluorocarbons [CFCs], and the Thinning of the Ozone Layer | |
| Abstract | Progress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}. | |
| 3582 K 80 pp. | |
| View Document | ||
