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TitleIsotopic Discrimination of Some Solutes in Liquid Ammonia
Author(s)Taube, H.; Viste, A.
Publication Date1966
Report NumberSU--326-P-6-17
Unique IdentifierACC0294
Other NumbersOSTI ID: 4465612
Research OrgThe University of Chicago, IL; Stanford University, CA
Contract NoAT(04-3)-326
Sponsoring OrgUS Atomic Energy Commission (AEC)
Other InformationJ. Phys. Chem., 70: 3763-7 (Dec. 15, 1966)
SubjectN20520 -- Chemistry -- Inorganic, Organic, & Physical Chemistry -- Isotope Exchange & Isotope Separation; Ammonia; Cations; Distribution; Isotope Separation; Low Temperature; Nitrogen Isotopes; Solvents ; Descriptor Groups (Splits): Potassium Compounds; Lithium Compounds; Sodium Compounds; Lead Compounds; Silver Compounds; Calcium Compounds; Potassium Compounds; Lithium Compounds; Sodium Compounds
KeywordsTracer Studies
Related Web PagesHenry Taube and Coordination Chemistry
AbstractThe nitrogen isotopic discrimination of some salts and metals, studies in liquid ammonia solution at -50C, decreases in magnitude in the order Pb{sup ++}, Ca{sup ++}, Li{sup +}, AG{sup +}, Na{sup +}, Li, K{sup +}, Na, K. The isotopic discrimination appears to provide qualitative information about the strength of the cation-solvent interaction in liquid ammonia.
529 K
15 pp.
 
View Document 
  


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