44 pp.
44 pp.
| 1467 K 44 pp. | |
| View Document | ||
| Title | Generalization of the Activated Complex Theory of Reaction Rates. I. Quantum Mechanical Treatment | |
| Author(s) | Marcus, R. A. | |
| Publication Date | 1964 | |
| Report Number | BNL-8127 | |
| Unique Identifier | ACC0264 | |
| Other Numbers | OSTI ID: 4005862 | |
| Research Org | Brookhaven National Laboratory (BNL), Upton, N.Y. and Polytechnic Institute of Brooklyn | |
| Contract No | AT(30-2)-Gen-16 | |
| Sponsoring Org | U.S. Atomic Energy Commission (AEC) | |
| Other Information | Journal of Chemical Physics (U.S.); Vol: 41 | |
| Subject | Chemistry; Equations; Mathematics; Numericals; Quantum Mechanics; Reaction Kinetics | |
| Related Web Pages | Rudolph A. Marcus and His Theory of Electron Transfer Reactions | |
| Abstract | In its usual form activated complex theory assumes a quasi-equilibrium between reactants and activated complex, a separable reaction coordinate, a Cartesian reaction coordinate, and an absence of interaction of rotation with internal motion in the complex. In the present paper a rate expression is derived without introducing the Cartesian assumption. The expression bears a formal resemblance to the usual one and reduces to it when the added assumptions of the latter are introduced. | |
| 1467 K 44 pp. | |
| View Document | ||
