1467 K
44 pp.
 
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TitleGeneralization of the Activated Complex Theory of Reaction Rates. I. Quantum Mechanical Treatment
Author(s)Marcus, R. A.
Publication Date1964
Report NumberBNL-8127
Unique IdentifierACC0264
Other NumbersOSTI ID: 4005862
Research OrgBrookhaven National Laboratory (BNL), Upton, N.Y. and Polytechnic Institute of Brooklyn
Contract NoAT(30-2)-Gen-16
Sponsoring OrgU.S. Atomic Energy Commission (AEC)
Other InformationJournal of Chemical Physics (U.S.); Vol: 41
SubjectChemistry; Equations; Mathematics; Numericals; Quantum Mechanics; Reaction Kinetics
Related Web PagesRudolph A. Marcus and His Theory of Electron Transfer Reactions
AbstractIn its usual form activated complex theory assumes a quasi-equilibrium between reactants and activated complex, a separable reaction coordinate, a Cartesian reaction coordinate, and an absence of interaction of rotation with internal motion in the complex. In the present paper a rate expression is derived without introducing the Cartesian assumption. The expression bears a formal resemblance to the usual one and reduces to it when the added assumptions of the latter are introduced.
1467 K
44 pp.
 
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