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40 pp.
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TitleGeneralization of the Activated Complex Theory of Reaction Rates. II. Classical Mechanical Treatment
Author(s)Marcus, R. A.
Publication Date1964
Report NumberBNL-8205
Unique IdentifierACC0263
Other NumbersOSTI ID: 4005955
Research OrgBrookhaven National Laboratory (BNL), Upton, N.Y. and Polytechnic Institute of Brooklyn
Contract NoAT(30-2)-Gen-16
Sponsoring OrgU.S. Atomic Energy Commission (AEC)
Other InformationJournal of Chemical Physics (U.S.); Vol: 41
SubjectChemistry; Energy; Equations; Free Energy; Interactions; Kinetic Energy; Mathematics; Reaction Kinetics; Rotation; Vibrations
Related Web PagesRudolph A. Marcus and His Theory of Electron Transfer Reactions
AbstractIn its usual classical form activated complex theory assumes a particular expression for the kinetic energy of the reacting system -- one associated with a rectilinear motion along the reaction coordinate. The derivation of the rate expression given in the present paper is based on the general kinetic energy expression.
1328 K
40 pp.
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