8 pp.
8 pp.
| 285 K 8 pp. | |
| View Document | ||
| Title | Controlled Synthesis of Polyenes by Catalytic Methods. Progress Report, December 1, 1992 -- November 30, 1993 | |
| Author(s) | Schrock, R. R. | |
| Publication Date | December 1993 | |
| Report Number | DOE/ER/13564--12 | |
| Unique Identifier | ACC0153 | |
| Other Numbers | Legacy ID: DE94004168; OSTI ID: 10108151; BR: KC0302010 | |
| Research Org | Massachusetts Institute of Technology, Cambridge, MA (United States) | |
| Contract No | FG02-86ER13564 | |
| Sponsoring Org | U.S. Department of Energy (USDOE), Washington, DC (United States) | |
| Subject | 37 Inorganic, Organic, Physical and Analytical Chemistry; 36 Materials Science; Polyenes; Synthesis; Polyacetylenes; Electric Conductivity; Copolymers; Nonlinear Optics; Molybdenum Complexes; Progress Report; Polymerization; Catalysts | |
| Related Web Pages | Richard Schrock, Robert Grubbs, and Metathesis Method in Organic Synthesis | |
| Abstract | Four studies are reported: living cyclopolymerization of diethyl dipropargylmalonate by Mo(CH-t-Bu)(NAr)[OCMe(CF{sub 3}){sub 2}]{sub 2} in dimethoxyethane, effect of chain length on conductivity of polyacetylene, nonlinear optical analysis of a series of triblock copolymers containing model polyenes, and synthesis of bifunctional hexafluoro-t-butoxide Mo species and their use as initiators in ROMP reactions. | |
| 285 K 8 pp. | |
| View Document | ||
