Chemistry of intermetallic hydrides
Certain intermetallic hydrides are safe, convenient and inexpensive hydrogen storage compounds. A particular advantage of such compounds is the ease with which their properties can be modified by small changes in alloy composition or preparation. This quality can be exploited to optimize their storage properties for particular applications, e.g. as intermetallic hydride electrodes in batteries. We will be concerned herein with the more important aspects of the thermodynamic and structural principles which regulate the behavior of intermetallic hydrogen systems and then illustrate their application using the archetype hydrides of LaNi5, FeTi and Mg alloys. The practical utility of these classes of materials will be briefly noted.
- Research Organization:
- Brookhaven National Lab., Upton, NY (United States)
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6084207
- Report Number(s):
- BNL-46778; CONF-911047-9; ON: DE92005000
- Resource Relation:
- Conference: 180. meeting of the Electrochemical Society, Phoenix, AZ (United States), 13-18 Oct 1991
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
ALLOYS
HYDRIDATION
HYDRIDES
THERMODYNAMIC MOLECULAR MODEL
ELECTRONIC STRUCTURE
IRON ALLOYS
LANTHANUM ALLOYS
MAGNESIUM ALLOYS
NICKEL BASE ALLOYS
REVIEWS
TITANIUM ALLOYS
CHEMICAL REACTIONS
DOCUMENT TYPES
HYDROGEN COMPOUNDS
MATHEMATICAL MODELS
MOLECULAR MODELS
NICKEL ALLOYS
RARE EARTH ALLOYS
080201* - Hydrogen- Chemisorption Storage
360202 - Ceramics
Cermets
& Refractories- Structure & Phase Studies