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Title: VOLATILITY STUDIES OF SOME FISSION PRODUCT FLUORIDES

Technical Report ·
DOI:https://doi.org/10.2172/4313816· OSTI ID:4313816

A preliminary study of the volatility behavior of molybdenum indicated that MoF/sub 5/ was converted to MoF/sub 6/ by F/sub 2/; MoF/sub 6/ and Tc fluoride are absorbed on NaF at 100; technetium fluoride is more strongly held than molybdenum fluoride on NaF; MoF/sub 6/ may not be completely trapped by a dry ice trap. The behavior of volatile fission product fluorides was such that (a) Ru and Nb fluorides were volatile from fused salts during fluorination, (b) Mo and technetium were not volatile during hydrofluorination but were in excess F/ sub 2/> 100 deg C(auth).

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
DOE Contract Number:
W-7405-ENG-26
NSA Number:
NSA-12-013008
OSTI ID:
4313816
Report Number(s):
CF-58-6-86
Resource Relation:
Other Information: Orig. Receipt Date: 31-DEC-58
Country of Publication:
United States
Language:
English