Synthesis of tobermorite: A cement phase expected under repository conditions
In this study I have synthesized tobermorite, Ca{sub 5}Si{sub 6}O{sub l6}(OH){sub 2.}4H{sub 2}0, a principal crystalline phase expected to form in cementitious materials subjected to elevated temperatures in a potential nuclear waste repository. Fluids interacting with these materials may have a profound effect on the integrity of the waste package and on transport of radionuclides. At ambient temperature, Portland cement reacts with water to form an amorphous calcium-silicate-hydrate (C-S-H) gel. At elevated temperatures, crystalline phases of various hydration states form. The C-S-H system has not been well characterized at elevated temperatures up to 250{degrees}C, which has been considered a bounding temperature for the potential Yucca Mountain repository. Physical, chemical, and thermodynamic data for these cement minerals that are predicted to be stable at these temperatures must be obtained from synthetic or natural samples to help predict fluid chemistry. For some of these minerals natural samples are difficult to obtain in sufficient quantity and purity. Therefore, monomineralic phases must be synthesized in order to unambiguously define their behavior. The synthetic or natural phases will be characterized as part of a comprehensive study to define the behavior of cementitious materials in a repository environment.
- Research Organization:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 25005
- Report Number(s):
- UCRL-JC-119131; CONF-950570-2; ON: DE95005917; TRN: 95:006969
- Resource Relation:
- Conference: International high-level radioactive waste management conference: progress toward understanding, Las Vegas, NV (United States), 1-5 May 1995; Other Information: PBD: Nov 1994
- Country of Publication:
- United States
- Language:
- English
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