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DOI 10.2172/6833612
Title Bench-scale studies on fluid-bed pyrolysis of wood
Creator/Author Mudge, L.K. ; Brown, M.D. ; Wilcox, W.A.
Publication Date1988 Aug 01
OSTI IdentifierOSTI ID: 6833612; Legacy ID: DE88015834
Report Number(s)PNL-6114
DOE Contract NumberAC06-76RL01830
DOI10.2172/6833612
Other Number(s)Other: ON: DE88015834
Resource TypeTechnical Report
Resource RelationOther Information: Portions of this document are illegible in microfiche products
Research OrgPacific Northwest Lab., Richland, WA (USA)
Subject09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BIOMASS CONVERSION PLANTS; BENCH-SCALE EXPERIMENTS; METHANE; PRODUCTION; PYROLYTIC GASES; CHEMICAL COMPOSITION; SYNTHESIS GAS; WOOD; PYROLYSIS; CARBON DIOXIDE; FLUIDIZED BEDS; HYDROGEN; NUMERICAL DATA; RENEWABLE RESOURCES; TEMPERATURE DEPENDENCE; ALKANES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; DATA; DECOMPOSITION; ELEMENTS; FLUIDS; GASES; HYDROCARBONS; INFORMATION; NONMETALS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PYROLYSIS PRODUCTS; RESOURCES; THERMOCHEMICAL PROCESSES
Description/AbstractThe primary objective of this study was to determine the effects of different contact gases and experimental conditions on product yields from fluid-bed wood pyrolysis. The yield of condensible hydrocarbons was of particular interest. The contact gases employed included carbon dioxide (CO/sub 2/), methane (CH/sub 4/), and hydrogen (H/sub 2/). Reaction temperatures ranged from 650/degree/C to 800/degree/C, and gas contact time was between 1 and 2 s. Tests with CO/sub 2/ contact gas used a secondary vessel of catalyst for cracking of condensibles generated in the primary gasifier. Results of earlier studies at PNL showed the effectiveness of various catalysts for destruction of condensible hydrocarbons. Analyses of results on the effects of contact gas, reaction temperature, gas contact time, and wood feed rate are presented in this report, along with a description of experimental equipment and methods. Data were obtained from single tests at each set of experimental conditions. Conditions were not repeated to determine the amount of experimental error. Material balance closures were generally quite good for the experimental tests, within 10%. 9 refs., 15 figs., 16 tabs.
Country of PublicationUnited States
LanguageEnglish
FormatMedium: ED; Size: Pages: 57
Availability NTIS, PC A04/MF A01; 1.
System Entry Date2008 Feb 08
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