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Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants

Description/Abstract

IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

DOI 10.2172/927111
Creator/Author: Elias Stefanakos ; Burton Krakow ; Jonathan Mbah
Publication Date:2007 Jul 31
OSTI Identifier:OSTI ID: 927111
DOE Contract Number:FG26-05NT42540
DOI:10.2172/927111
Other Number(s):TRN: US200811%%194
Resource Type:Technical Report
Coverage:Final
Research Org:University Of South Florida Incorporated
Sponsoring Org:USDOE
Subject:08 HYDROGEN; ELECTROLYSIS; ELECTROLYTES; HYDROGEN; HYDROGEN PRODUCTION; HYDROGEN SULFIDES; POWER GENERATION; POWER PLANTS; SULFUR; SYNTHESIS GAS; WATER
Country of Publication:United States
Language:English
Update Date:2008 Jun 12

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