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Diode laser excited optogalvanic spectroscopy of glow discharges

Description/Abstract

The development of diode-laser-excited isotopically-selective optogalvanic spectroscopy (OGS) of uranium metal, oxide and fluoride in a glow discharge (GD) is presented. The technique is useful for determining isotopic ratios of {sup 235}U/({sup 235}U + {sup 238}U) in the above samples. The precision and accuracy of this determination is evaluated, and a study of experimental parameters pertaining to optimization of he measurement is discussed. Application of the GD-OGS to other f-transition elements is also described.

Creator/Author: Barshick, C.M. ; Shaw, R.W. ; Post-Zwicker, A., Young, J.P. ; Ramsey, J.M.
Publication Date:1996 Oct 01
OSTI Identifier:OSTI ID: 392737; Legacy ID: DE96014601
Report Number(s):CONF-960686--3
DOE Contract Number:AC05-96OR22464
Other Number(s):Other: ON: DE96014601; TRN: 96:029080
Resource Type:Conference
Resource Relation:Conference: 8. international symposium on resonance ionization spectroscopy and its applications (RIS-96), State College, PA (United States), 30 Jun - 5 Jul 1996; Other Information: PBD: [1996]
Research Org:Oak Ridge National Lab., TN (United States)
Sponsoring Org:USDOE, Washington, DC (United States)
Subject:66 PHYSICS; GLOW DISCHARGES; SPECTROSCOPY; URANIUM 235; URANIUM 238; CERIUM; SEMICONDUCTOR LASERS; URANIUM OXIDES; URANIUM FLUORIDES; ISOTOPE RATIO; INFRARED RADIATION; OPTICAL PUMPING; OSCILLOGRAPHS
Country of Publication:United States
Language:English
Format: Size: 4 p.
Availability: INIS; OSTI as DE96014601
To purchase this media from NTIS, click here
Update Date:2009 Nov 10

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