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DOI 10.2172/135056
Title Current status of environmental, health, and safety issues of lithium ion electric vehicle batteries
Creator/Author Vimmerstedt, L.J. ; Ring, S. ; Hammel, C.J.
Publication Date1995 Sep 01
OSTI IdentifierOSTI ID: 135056; Legacy ID: DE95009295
Report Number(s)NREL/TP--463-7673
DOE Contract NumberAC36-83CH10093
DOI10.2172/135056
Other Number(s)Other: ON: DE95009295; TRN: TRN: 95:008674
Resource TypeTechnical Report
Resource RelationOther Information: PBD: Sep 1995
Research OrgNational Renewable Energy Lab., Golden, CO (United States)
Sponsoring OrgUSDOE, Washington, DC (United States)
Subject25 ENERGY STORAGE ;32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ELECTRIC-POWERED VEHICLES; ENERGY STORAGE SYSTEMS; LITHIUM-CHLORINE BATTERIES; COMMERCIALIZATION; RISK ASSESSMENT
Description/AbstractThe lithium ion system considered in this report uses lithium intercalation compounds as both positive and negative electrodes and has an organic liquid electrolyte. Oxides of nickel, cobalt, and manganese are used in the positive electrode, and carbon is used in the negative electrode. This report presents health and safety issues, environmental issues, and shipping requirements for lithium ion electric vehicle (EV) batteries. A lithium-based electrochemical system can, in theory, achieve higher energy density than systems using other elements. The lithium ion system is less reactive and more reliable than present lithium metal systems and has possible performance advantages over some lithium solid polymer electrolyte batteries. However, the possibility of electrolyte spills could be a disadvantage of a liquid electrolyte system compared to a solid electrolyte. The lithium ion system is a developing technology, so there is some uncertainty regarding which materials will be used in an EV-sized battery. This report reviews the materials presented in the open literature within the context of health and safety issues, considering intrinsic material hazards, mitigation of material hazards, and safety testing. Some possible lithium ion battery materials are toxic, carcinogenic, or could undergo chemical reactions that produce hazardous heat or gases. Toxic materials include lithium compounds, nickel compounds, arsenic compounds, and dimethoxyethane. Carcinogenic materials include nickel compounds, arsenic compounds, and (possibly) cobalt compounds, copper, and polypropylene. Lithiated negative electrode materials could be reactive. However, because information about the exact compounds that will be used in future batteries is proprietary, ongoing research will determine which specific hazards will apply.
Country of PublicationUnited States
LanguageEnglish
FormatMedium: ED; Size: 51 p.
Availability OSTI as DE95009295
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System Entry Date2009 Nov 05
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