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Title: Corrosion of stainless and carbon steels in molten mixtures of industrial nitrates

Technical Report ·
DOI:https://doi.org/10.2172/10141843· OSTI ID:10141843
;  [1]; ;  [2]
  1. Sandia National Labs., Livermore, CA (United States)
  2. Sandia National Labs., Albuquerque, NM (United States)

Corrosion behavior of two stainless steels and carbon steel in mixtures of NaNO{sub 3} and KNO{sub 3} was evaluated to determine if impurities found in commodity grades of alkali nitrates aggravate corrosivity as applicable to an advanced solar thermal energy system. Corrosion tests were conducted for 7000 hours with Types 304 and 316 stainless steels at 570C and A36 carbon steel at 316C in seven mixtures of NaNO{sub 3} and KNO{sub 3} containing variations in impurity concentrations. Corrosion tests were also conducted in a ternary mixture of NaNO{sub 3}, KNO{sub 3}, and Ca(NO{sub 3}){sub 2}. Corrosion rates were determined by descaled weight losses while oxidation products were examined by scanning electron microscopy, electron microprobe analysis, and X-ray diffraction. The nitrate mixtures were periodically analyzed for changes in impurity concentrations and for soluble corrosion products.

Research Organization:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
10141843
Report Number(s):
SAND-94-8211; ON: DE94009866; BR: GB0103012
Resource Relation:
Other Information: PBD: Mar 1994
Country of Publication:
United States
Language:
English