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Title: Constitutive response of two plastic-bonded explosive binder materials as a function of temperature and strain-rate

Conference ·
OSTI ID:977798

Recently, interest has been shown concerning the mechanical response of plastic-bonded explosives (PBX) and propellants to enable the development of predictive materials models describing the mechanical behavior of these composites. Accordingly, detailed information about the constitutive response is crucial. Compression measurements were conducted on two explosive formulation binders, extruded Estane{trademark} 5703 (hereafter referred to as Estane) and plasticized Estane as a function of temperature from -60 C to +23 C using a specially-designed split Hopkinson pressure bar (strain rate of {approx} 2800 s{sup -1}) and quasi-stattically (strain rates from {approx} 0.001 to 1 s{sup -1}) using a hydraulic load frame. The mechanical response of the Estane was found to exhibit a stronger dependency on strain rate and temperature and higher flow strength for similar test conditions of the materials tested. Plasticized Estane was less sensitively dependent on strain rate and temperature. The visco-elastic recovery of both binders is seen to dominate the mechanical behavior at temperatures above the glass transition temperature (T{sub g}). The binders exhibited increasing elastic loading moduli, E, with increasing strain rate or decreasing temperature, which is similar to other polymeric materials. There is a pronounced shift in the apparent T{sub g} to higher temperatures as the strain rate is increased. At low strain rates the binders exhibit a yield behavior followed by a drop in the flow stress which may or may not recover. At high strain rates the load drop does not occur and the flow stresses level out. A discussion of the Hopkinson bar technique as applied to polymeric or low impedance materials is described in detail.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
OSTI ID:
977798
Report Number(s):
LA-UR-04-5465; TRN: US201012%%731
Resource Relation:
Conference: Submitted to Plasticity '05, 11th International Symposium on Plasticity, Kauai, Hawaii, Jan. 3-9, 2005
Country of Publication:
United States
Language:
English