skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ozone production rate and hydrocarbon reactivity in 5 urban areas: A cause of high ozone concentration in Houston

Journal Article · · Geophysical Research Letters
 [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3]
  1. Atmospheric Sciences Division Brookhaven National Laboratory Upton New York USA
  2. Chemistry/Physics Department SUNY/Old Westbury Old Westbury New York USA
  3. Chemistry Department and Centre for Atmospheric Research York University Toronto Ontario Canada

Observations of ozone (O3) and O3 precursors taken from aircraft flights over Houston, TX, Nashville, TN; New York, NY; Phoenix, AZ, and Philadelphia, PA show that high concentrations of reactive volatile organic compounds (VOCs) in the Houston atmosphere lead to calculated O3 production rates that are 2 to 5 times higher than in the other 4 cities even though NOx concentrations are comparable. Within the Houston metropolitan area, concentrations of VOCs and O3 production rates are highest in the Ship Channel region; the location of one of the largest petrochemical complexes in the world. As a consequence the concentration of O3 in the Houston metropolitan area has recently exceeded 250 ppb, the highest value observed in the U.S within the past 5 years.

Research Organization:
SUNY Research Foundation on behalf of College at Old Westbury
Sponsoring Organization:
USDOE - Office of Energy Research (ER)
DOE Contract Number:
FG02-98ER62586
OSTI ID:
895151
Report Number(s):
DOE/ER/62586-1; Pub7
Journal Information:
Geophysical Research Letters, Vol. 29, Issue 10; ISSN 0094-8276
Publisher:
American Geophysical Union (AGU)
Country of Publication:
United States
Language:
English

References (17)

The role of biogenic hydrocarbons in urban photochemical smog: Atlanta as a case study journal September 1988
Ozone precursor relationships in the ambient atmosphere journal January 1992
Analysis of O3 formation during a stagnation episode in central Tennessee in summer 1995 journal April 2000
The evolution of the boundary layer and its effect on air chemistry in the Phoenix area journal September 2000
Effect of regional‐scale transport on oxidants in the vicinity of Philadelphia during the 1999 NE‐OPS field campaign journal August 2002
Airborne measurements of isoprene, CO, and anthropogenic hydrocarbons and their implications journal April 2000
Reported emissions of organic gases are not consistent with observations journal June 1997
Low and high NO x tropospheric photochemistry journal January 1994
Ozone production in the New York City urban plume journal June 2000
Sensitivity of ozone production rate to ozone precursors journal August 2001
Atmospheric chemistry and distribution of formaldehyde and several multioxygenated carbonyl compounds during the 1995 Nashville/Middle Tennessee Ozone Study journal September 1998
Analysis of motor vehicle sources and their contribution to ambient hydrocarbon distributions at urban sites in Toronto during the Southern Ontario oxidants study journal June 1996
The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes journal February 1990
The use of NO y , H 2 O 2 , and HNO 3 as indicators for ozone-NO x -hydrocarbon sensitivity in urban locations journal January 1995
The second generation regional acid deposition model chemical mechanism for regional air quality modeling journal January 1990
Analysis of radical propagation efficiency to assess ozone sensitivity to hydrocarbons and NO x : 1. Local indicators of instantaneous odd oxygen production sensitivity journal April 2000
Models and observations of the impact of natural hydrocarbons on rural ozone journal October 1987

Similar Records

EFFICIENCY OF OZONE PRODUCTION IN THE HOUSTON PLUME.
Conference · Mon Oct 01 00:00:00 EDT 2001 · OSTI ID:895151

An ozone episode in the Philadelphia metropolitan area
Journal Article · Thu Jan 01 00:00:00 EST 2004 · Journal of Geophysical Research · OSTI ID:895151

OZONE PRODUCTION IN URBAN PLUMES.
Conference · Mon Sep 17 00:00:00 EDT 2001 · OSTI ID:895151