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Title: Layer growth in Au--Pb/In solder joints

Journal Article · · Metall. Trans., A; (United States)
DOI:https://doi.org/10.1007/BF02656596· OSTI ID:7321949

The solid state reaction between a Pb-In solder alloy and thin film Au has been investigated at ten aging temperatures ranging from 70 to 170/sup 0/C. Also, bulk Au-solder samples were aged at 150/sup 0/C for metallographic analysis. No significant difference was found between the aging behavior of thin and bulk Au specimens. A thin single phase layer of Au/sub 9/In/sub 4/ was found adjacent to Au while a thick two-phase layer of AuIn/sub 2/ and Pb was found between Au/sub 9/In/sub 4/ and solder. The Pb phase was shown to have considerable mobility and able to ripen at room temperature. Peculiar planar interface instabilities and voids in the Au-Au/sub 9/In/sub 4/ interface were found. Although the total layer thickness vs aging time data could be closely fitted with a power law relationship, it was shown that a linear relationship also fits well and is consistent with accepted metallurgical concepts. An activation energy of 0.61 eV was found by regression analysis of the intermetallic growth kinetics.

Research Organization:
Sandia Labs., Albuquerque, NM
OSTI ID:
7321949
Journal Information:
Metall. Trans., A; (United States), Vol. 7:8
Country of Publication:
United States
Language:
English