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Title: Rapid pressure swing absorption cleanup of post-shift reactor synthesis gas

Technical Report ·
DOI:https://doi.org/10.2172/7233376· OSTI ID:7233376
; ;  [1]
  1. New Jersey Inst. of Tech., Newark, NJ (United States)

This investigation is concerned with the separation of gas mixtures using a novel concept of rapid pressure swing absorption (RAPSAB) of gas in a stationary absorbent liquid through gas-liquid interfaces immobilized in the pore mouths of hydrophobic microporous membranes. The process is implemented in a module well-packed with hydrophobic microporous hollow fiber membranes. The specific objectives are (1) to develop a theoretical model which will provide guidelines for selecting an efficient RAPSAB process cycle which includes desorption; (2) to demonstrate the concept experimentally with a simple gas mixture (e.g., Co{sub 2}-N{sub 2}) and a simple absorbent liquid such as water, and (3) to extend the concept to reactive absorbent liquids for the separation of CO, Co{sub 2} from the post-shift reactor synthesis gas. A simplified theoretical description of the novel rapid pressure swing absorption process has been developed.

Research Organization:
Stevens Inst. of Tech., Hoboken, NJ (United States). Dept. of Chemistry and Chemical Engineering; New Jersey Inst. of Tech., Newark, NJ (United States)
Sponsoring Organization:
USDOE; USDOE, Washington, DC (United States)
DOE Contract Number:
FG22-90PC90300
OSTI ID:
7233376
Report Number(s):
DOE/PC/90300-T6; ON: DE92017968
Country of Publication:
United States
Language:
English