Combined isotopic, chromatographic, and spectral determination of carbon dioxide in pure inorganic gases (survey)
There are major problems in determining CO/sub 2/ in pure inorganic gases on account of difficulties in making and storing standard specimens with low impurity contents. A combined isotopic, chromatographic, and spectral method can be employed based on cryogenic adsorption, which in principle allows one to determine low values of minor components without using such specimens. The method is used in this paper to determine CO/sub 2/ in pure inorganic gases: He, Ne, Ar, N/sub 2/, and H/sub 2/. The method includes the following steps: gas sampling; adding a known amount of carbon dioxide enriched in /sup 18/O; physicochemical transformation of the resulting analytical mixture (AM); and spectroscopic derivation of the isotope ratio c/sub C/sup 16/O/sub 3///c/sub C/sup 18/O/sub 2// = c/sub 1//c/sub 2/, with calculation of the unknown content c/sub x/ in mole %.
- Research Organization:
- Zhdanov Univ., Leningrad (USSR)
- OSTI ID:
- 7171610
- Journal Information:
- Ind. Lab. (Engl. Transl.); (United States), Vol. 53:6; Other Information: Translated from Zavod. Lab.; 53: No. 6, 22-26(Jun 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ARGON
GAS ANALYSIS
CARBON DIOXIDE
GAS CHROMATOGRAPHY
RADIOCHEMICAL ANALYSIS
SPECTROSCOPY
HELIUM
HYDROGEN
NEON
NITROGEN
ADSORPTION
CRYOGENICS
ISOTOPE RATIO
LABELLED COMPOUNDS
OXYGEN 16
OXYGEN 18
SENSITIVITY
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
ELEMENTS
EVEN-EVEN NUCLEI
FLUIDS
GASES
ISOTOPES
LIGHT NUCLEI
NONMETALS
NUCLEI
OXIDES
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
QUANTITATIVE CHEMICAL ANALYSIS
RARE GASES
SEPARATION PROCESSES
SORPTION
STABLE ISOTOPES
400101* - Activation
Nuclear Reaction
Radiometric & Radiochemical Procedures
400102 - Chemical & Spectral Procedures
400105 - Separation Procedures