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Title: Development of cementitious grouts for the incorporation of radioactive wastes. Part 2. Continuation of cesium and strontium leach studies. [Hydrofracture]

Technical Report ·
DOI:https://doi.org/10.2172/7150093· OSTI ID:7150093

Additional leach studies were completed on the leachability of cesium and strontium from simulated hydrofracture grout. These studies followed the test method proposed by IAEA or a modification which exposed smaller specimens with a higher surface-to-volume ratio to a larger volume of leachant. Results showed that the amount of cesium or strontium leached from the grout varied directly with the degree of drying during curing and inversely with the time of curing. The leachability also depends on the composition of the leachant and varies in the order: distilled water greater than tap water greater than grout water. The total waste concentration had little effect on the leachability of either cesium or strontium. The credibility of the laboratory results was substantiated by a short-term continuous leach test made on a fragment of a core sample of actual hydrofracture grout. The modified effective diffusivities (10/sup -11/ to 10/sup -10/ cm/sup 2//s) calculated from these limited data were comparable to those obtained from laboratory studies containing Grundite clay. These tests also confirmed the effect of various clays on the leachability of cesium and the importance of leachant renewal frequency on the leach rate.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
DOE Contract Number:
W-7405-ENG-26
OSTI ID:
7150093
Report Number(s):
ORNL-5142; TRN: 76-021775
Country of Publication:
United States
Language:
English