Reactions of iminium ligands with alkynes. Addition of HC triple bond CCO sub 2 Me to Os sub 3 (CO) sub 10 (. mu. -H sub 2 CNMe sub 2 )(. mu. -H)
- Univ. of South Carolina, Columbia (USA)
The reaction of Os{sub 3}(CO){sub 10}({mu}-H{sub 2}CNMe{sub 2})({mu}-H) (1) with HC{triple bond}CCO{sub 2}Me has yielded three new products, Os{sub 3}(CO){sub 8}({mu}-CNMe{sub 2}) ({mu}{sub 3}-CH{sub 2}C(CO{sub 2}Me)C(CO{sub 2}Me)CH) (3, 7%{degree}), Os{sub 3}(CO){sub 9}({mu}{sub 3}-Me{sub 2}NCCC(H)(CO{sub 2}Me))({mu}-H) (4, 20%), and Os{sub 3}(CO){sub 9}({mu}{sub 3}-H{sub 2}CNMe{sub 2}CH{sub 2}CCO{sub 2}Me) (5, 6%). Compounds 3-5 were characterized by IR, {sup 1}H NMR, and single-crystal X-ray diffraction analyses. Crystal data for 3: space group, P2{sub 1}/n, a = 9.998 (3) {angstrom}, b = 14.229 (4), c = 17.926 (3) {angstrom}, {beta} = 104.67 (2){degree}, R = 0.028 for 2616 reflections. Crystal data for 4: space group, P1, a = 10.623 (2) {angstrom}, b = 12.877 (2) {angstrom}, c = 8.531 (2) {angstrom}, {alpha} = 102.18 (1){degree}, {beta} = 102.14 (2){degree}, {gamma} = 85.85 (1){degree}, R = 0.025 for 2508 reflections. Crystal data for 5: space group P2{sub 1}/c, a = 8.778 (4) {angstrom}, b = 15.836 (3) {angstrom}, c = 16.029 (4) {angstrom}, {beta} = 105.61 (3){degree}, R = 0.052 for 2907 reflections.
- OSTI ID:
- 7108044
- Journal Information:
- Organometallics; (USA), Vol. 9:2; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
Similar Records
Carbon dioxide chemistry and electrochemistry of a binuclear cradle complex of Ni(0), Ni/sub 2/(. mu. -CNMe)(CNMe)/sub 2/(PPh/sub 2/CH/sub 2/PPh/sub 2/)/sub 2/
Dinuclear cyclopentadienyl carbonyl and alkyne complexes of niobium(II) and tantalum(II). Structures of ((C sub 5 H sub 4 Me)Nb(. mu. -Cl)(CO) sub 2 ) sub 2 , ((C sub 5 H sub 4 Me)Nb(. mu. -Cl)(ArC triple bond CAr)) sub 2 , and ((C sub 5 Me sub 5 )Ta(. mu. -Cl)(CO) sub 2 ) sub 2
Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
ORGANOMETALLIC COMPOUNDS
SYNTHESIS
OSMIUM COMPLEXES
ALKYNES
CALCULATION METHODS
CHEMICAL BONDS
CRYSTAL STRUCTURE
DATA ANALYSIS
EXPERIMENTAL DATA
LIGANDS
MEASURING INSTRUMENTS
MEASURING METHODS
COMPLEXES
DATA
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
360104 - Metals & Alloys- Physical Properties