skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Equivalences and lower ignition limits of coal dust and methane mixtures

Technical Report ·
OSTI ID:7081247

This study was undertaken to obtain some fundamental information about hazardous mixtures of coal dust and methane (firedamp) likely to occur in mines. Fuel concentration limits for ignition of mixtures of coal dust, methane, and air have been determined by a hot-gas ignition method. The limiting concentration of each of the two fuels was usually less than that corresponding to its lean flammability limit in air. The lean limits of flammability of coal dust vary with the type and size of the dust; in this study coal dust concentrations were less than 80 mg/liter. Ignition jets were turbulent pulses (emerging from a channel of 0.5-cm diam) resulting from explosions of stoichiometric mixtures of methane, oxygen, and nitrogen. The objectives were to establish quantitative relations between concentrations of each fuel at ignition limits of hybrid mixtures and to study the mechanism of ignition by hot turbulent gases. Empirical equations were fitted to concentrations for four coals, namely, Pittsburgh seam (sizes A, B, and C), Sewell No. 2 seam, Pocahontas No. 3 seam, and anthracite. Equivalences of coal dust to methane were computed from these equations; equivalence being defined as -..delta..c/..delta..m where c is the coal dust concentrated and m is the methane concentration, each in milligrams per liter of air. It was found that the equivalence increases as the temperature of the hot-gas jet decreases. In general, the equivalence is also an inverse function of volatile content of the coal and a direct function of the particle size. However, volatile content in itself is not a sufficient correlating variable, nor is the specific surface area of the coal dust. Some evidence of a synergistic combination of coal dust and methane was obtained in certain concentration ranges.

Research Organization:
Bureau of Mines, Washington, D.C. (USA)
OSTI ID:
7081247
Report Number(s):
BM-RI-6931
Country of Publication:
United States
Language:
English