Preconversion catalytic deoxygenation of phenolic functional groups
Technical Report
·
OSTI ID:7046283
The deoxygenation of phenols is a conceptually simple, but unusually difficult chemical transformation to achieve. The phenolic C-O bond energy of 103 kcal/mol is as strong as a benzene C-H bond and over 10 kcal/mol stronger than the C-O bonds of methanol and ethanol. The consequence of this is that the hydrogenation/deoxygenation methods in current use require severe conditions and give low selectivities. The ongoing research described herein is based on the unprecedented, but thermodynamically promising, use of carbon monoxide as the oxygen atom acceptor for the catalytic deoxygenation of phenols.
- Research Organization:
- Purdue Univ., Lafayette, IN (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-89PC89770
- OSTI ID:
- 7046283
- Report Number(s):
- DOE/PC/89770-T8; ON: DE92015424
- Country of Publication:
- United States
- Language:
- English
Similar Records
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, May 31, 1990--December 31, 1990
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, January 1, 1992--March 31, 1992
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technial progress report, January 1, 1992--March 31, 1992
Technical Report
·
Mon Dec 31 00:00:00 EST 1990
·
OSTI ID:7046283
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, January 1, 1992--March 31, 1992
Technical Report
·
Sat Aug 01 00:00:00 EDT 1992
·
OSTI ID:7046283
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technial progress report, January 1, 1992--March 31, 1992
Technical Report
·
Sat Aug 01 00:00:00 EDT 1992
·
OSTI ID:7046283
Related Subjects
01 COAL, LIGNITE, AND PEAT
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM OXIDES
CATALYTIC EFFECTS
CHEMICAL BONDS
CLEAVAGE
COBALT
IRON OXIDES
MOLYBDENUM
NICKEL
OXYGEN COMPOUNDS
REMOVAL
SILICON OXIDES
CARBON MONOXIDE
HYDROGENATION
PHENOLS
PROGRESS REPORT
THERMODYNAMICS
ALUMINIUM COMPOUNDS
AROMATICS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DOCUMENT TYPES
ELEMENTS
HYDROXY COMPOUNDS
IRON COMPOUNDS
METALS
MICROSTRUCTURE
ORGANIC COMPOUNDS
OXIDES
SILICON COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
010402* - Coal
Lignite
& Peat- Purification & Upgrading
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM OXIDES
CATALYTIC EFFECTS
CHEMICAL BONDS
CLEAVAGE
COBALT
IRON OXIDES
MOLYBDENUM
NICKEL
OXYGEN COMPOUNDS
REMOVAL
SILICON OXIDES
CARBON MONOXIDE
HYDROGENATION
PHENOLS
PROGRESS REPORT
THERMODYNAMICS
ALUMINIUM COMPOUNDS
AROMATICS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DOCUMENT TYPES
ELEMENTS
HYDROXY COMPOUNDS
IRON COMPOUNDS
METALS
MICROSTRUCTURE
ORGANIC COMPOUNDS
OXIDES
SILICON COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
010402* - Coal
Lignite
& Peat- Purification & Upgrading
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties