Compositions and method for controlling precipitation when acidizing sour wells
This patent describes an acidizing composition for treating a sour well. It comprises: a base acid solution having an initial ph below 1.9; an iron sequestering agent to combine with iron present in the solution comprising at least one compound selected from the group consisting of aminopolycarboxylic acids, hydroxycarboxylic acids, cyclic polyethers and derivatives of the acids and ethers present in an amount of from about 0.25 to about 5 percent by weight of the acid solution; and a sulfide modifier to combine with sulfides present in the solution comprising at least one member selected from the group consisting of an aldehyde, acetal, hemiacetal and any other compound capable of forming an aldehyde in solution, present in an amount of from about 1 to about 4 percent by weight of the acid solution, whereby precipitation of ferric hydroxide, ferrous sulfide and elemental sulfur is inhibited as acid spending occurs.
- Assignee:
- Halliburton Co., Duncan, OK
- Patent Number(s):
- US 4888121; A
- Application Number:
- PPN: US 7-177743A
- OSTI ID:
- 6916041
- Resource Relation:
- Patent File Date: 5 Apr 1988
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
03 NATURAL GAS
NATURAL GAS WELLS
ACIDIZATION
OIL WELLS
SULFUR
INHIBITION
ALDEHYDES
CARBOXYLIC ACIDS
CHEMICAL COMPOSITION
ENHANCED RECOVERY
IRON COMPOUNDS
IRON HYDROXIDES
IRON SULFIDES
POLYETHYLENE GLYCOLS
PROCESS SOLUTIONS
WELL STIMULATION
ALCOHOLS
CHALCOGENIDES
DISPERSIONS
ELEMENTS
GLYCOLS
HYDROGEN COMPOUNDS
HYDROXIDES
HYDROXY COMPOUNDS
MIXTURES
NONMETALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
POLYMERS
RECOVERY
SOLUTIONS
STIMULATION
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
WELLS
020300* - Petroleum- Drilling & Production
030300 - Natural Gas- Drilling
Production
& Processing