On the relationship of high coercivity and L1{sub 0} ordered phase in CoPt and FePt thin films

Journal Article · Fri Oct 01 00:00:00 EDT 1999 · Journal of Applied Physics

DOI:https://doi.org/10.1063/1.371397· OSTI ID:686516

Ristau, R A; Barmak, K ^[1]; Lewis, L H ^[2]; Coffey, K R; Howard, J K ^[3]

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1. Department of Materials Science and Engineering, Lehigh University, Bethlehem, Pennsylvania 18015 (United States)
2. Materials Science Division, Department of Applied Science, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States)
3. IBM Storage Systems Division, 5600 Cottle Road, San Jose, California 95193 (United States)

The microstructure and the room-temperature hysteretic magnetic properties of sputtered, 10 nm thin films of equiatomic binary alloys of CoPt and FePt were characterized using transmission electron microscopy (TEM) and a superconducting quantum interference device (SQUID) magnetometer. A transformation from an atomically disordered, face-centered-cubic structure to the L1{sub 0} ordered structure occurred during postdeposition annealing and was characterized using digital analysis of dark-field TEM images. The transformation was observed to follow first-order nucleation and growth kinetics, and the ordered volume fraction transformed was quantified at numerous points during the transformation. The ordered volume fraction was then compared to the magnetic coercivity data obtained from the SQUID magnetometer. In contrast to the relationship most commonly described in the literature, that the highest coercivity corresponds to a two phase ordered/disordered mixture, the maximum value for coercivity in this study was found to correspond to the fully ordered state. Furthermore, in samples that were less than fully ordered, a direct relationship between ordered volume fraction and coercivity was observed for both CoPt and FePt. The proposed mechanism for the high coercivity in these films is an increasing density of magnetic domain wall pinning sites concurrent with an increasing fraction of ordered phase. {copyright} {ital 1999 American Institute of Physics.} thinsp

• OSTI ID: 686516
• Journal Information: Journal of Applied Physics, Vol. 86, Issue 8; Other Information: PBD: Oct 1999
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
PERMANENT MAGNETS
NUCLEATION
ANNEALING
COBALT ALLOYS
PLATINUM ALLOYS
IRON ALLOYS
MICROSTRUCTURE
HYSTERESIS
THIN FILMS
PHASE TRANSFORMATIONS
TRANSMISSION ELECTRON MICROSCOPY
SQUID DEVICES
COERCIVE FORCE
MAGNETIC PROPERTIES