Thermochemical cyclic system for decomposing H/sub 2/O and/or CO/sub 2/ by means of cerium-titanium-sodium-oxygen compounds
A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO/sub 2/), titanium dioxide (TiO/sub 2/) and sodium titanate (Na/sub 2/TiO/sub 3/) to form sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) and oxygen. Sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) reacted with sodium carbonate (Na/sub 2/CO/sub 3/) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.
- DOE Contract Number:
- W-7405-ENG-26
- Assignee:
- Dept. of Energy
- OSTI ID:
- 6579223
- Country of Publication:
- United States
- Language:
- English
Similar Records
Thermochemical cyclic system for decomposing H2O and/or CO2 by means of cerium-titanium-sodium-oxygen compounds
Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein
Related Subjects
HYDROGEN PRODUCTION
THERMOCHEMICAL PROCESSES
CARBON DIOXIDE
CARBON MONOXIDE
CERIUM OXIDES
PRODUCTION
SODIUM COMPOUNDS
TITANATES
TITANIUM OXIDES
WATER
ALKALI METAL COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CERIUM COMPOUNDS
CHALCOGENIDES
HYDROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPOUNDS
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
080102* - Hydrogen- Production- Thermochemical Processes