Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction study of the crystal and molecular structure of (. mu. -H)/sub 2/Os/sub 3/(CO)/sub 10/(. mu. -CH/sub 2/)
The crystal and molecular structure of (..mu..-H)/sub 2/Os/sub 3/(CO)/sub 10/(..mu..-CH/sub 2/) has been determined by using single-crystal neutron diffraction. The complex crystallizes in the orthorhombic space group Pn2/sub 1/a with lattice parameters at 110 K of a = 18.502(9), b = 10.096(5), and c = 8.763(4)A. The molecule consists of a triangular array of Os atoms with one nonbridged edge (Os-Os = 2,855(3)A), one edge bridged by a single hydride (Os-Os = 3.053(3)A), and a third edge doubly bridged by a hydride atom and a methylene ligand (Os-Os = 2,824(3)A). The complex contains no terminal hydride ligands. The methylene carbon atom has a distorted tetrahedral geometry with an Os-C-Os angle of 82.1(1)/sup 0/ and a H-C-H angle of 106.0(8)/sup 0/.
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 6480722
- Journal Information:
- Inorg. Chem.; (United States), Vol. 18:2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HYDROCARBONS
CONFIGURATION MIXING
HYDROGEN
OSMIUM COMPLEXES
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENTS
BOND ANGLE
CRYSTAL STRUCTURE
INTERATOMIC DISTANCES
LATTICE PARAMETERS
LOW TEMPERATURE
MOLECULAR STRUCTURE
NEUTRON DIFFRACTION
ORTHORHOMBIC LATTICES
TEMPERATURE DEPENDENCE
COHERENT SCATTERING
COMPLEXES
CRYOGENIC FLUIDS
CRYSTAL LATTICES
DIFFRACTION
DISTANCE
ELEMENTS
FLUIDS
INTERACTIONS
METALS
NONMETALS
ORGANIC COMPOUNDS
SCATTERING
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties