Hydrogenation of small molecules by transition metal cluster hydrides. Reaction of H/sub 2/Os/sub 3/(CO)/sub 10/ with carbon disulfide
Journal Article
·
· J. Am. Chem. Soc.; (United States)
H/sub 2/Os/sub 3/(CO)/sub 10/ was refluxed with carbon disulfide for 34 hr. The reaction product was analyzed as H/sub 2/CS/sub 2/(HOs/sub 3/(CO)/sub 10/)/sub 2/ by IR, /sup 1/H NMR, and x-ray crystallography. The molecular structure is illustrated. The nature of the cluster bonding is discussed. Carbon--sulfur bond distances are listed. The cluster reduction has produced a CH/sub 2/S/sub 2//sup 2 -/ unit which might be a precursor to dithioacetal. 1 figure.
- Research Organization:
- Yale Univ., New Haven, CT
- OSTI ID:
- 6480177
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 101:5
- Country of Publication:
- United States
- Language:
- English
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Wed Sep 12 00:00:00 EDT 1979
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6480177
Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(trans-dpmn) and 1,2-Os3(CO)10(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os3(CO)10(dpmn) and Isomer-Dependent Diphosphine Ligand Activation
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Wed Jul 23 00:00:00 EDT 2014
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OSTI ID:6480177
+1 more
Aspects of the hydrogenation of carbon disulfide by transition-metal cluster compounds. The reactions of carbon disulfide with hydridotriosmium-carbonyl clusters
Journal Article
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Wed Feb 11 00:00:00 EST 1981
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6480177
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON SULFIDES
CHEMICAL REACTIONS
OSMIUM COMPLEXES
CHEMICAL REACTION YIELD
STRUCTURAL CHEMICAL ANALYSIS
CARBONYL RADICALS
CRYSTAL STRUCTURE
EXPERIMENTAL DATA
INFRARED SPECTRA
INTERATOMIC DISTANCES
ISOLATED VALUES
LATTICE PARAMETERS
MOLECULAR STRUCTURE
NUCLEAR MAGNETIC RESONANCE
ORGANIC SULFUR COMPOUNDS
PRECURSOR
SPACE GROUPS
SYNTHESIS
X-RAY DIFFRACTION
CARBON COMPOUNDS
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
DATA
DATA FORMS
DIFFRACTION
DISTANCE
INFORMATION
MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
RADICALS
RESONANCE
SCATTERING
SPECTRA
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPLEXES
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400302 - Organic Chemistry- Isotope Effects- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON SULFIDES
CHEMICAL REACTIONS
OSMIUM COMPLEXES
CHEMICAL REACTION YIELD
STRUCTURAL CHEMICAL ANALYSIS
CARBONYL RADICALS
CRYSTAL STRUCTURE
EXPERIMENTAL DATA
INFRARED SPECTRA
INTERATOMIC DISTANCES
ISOLATED VALUES
LATTICE PARAMETERS
MOLECULAR STRUCTURE
NUCLEAR MAGNETIC RESONANCE
ORGANIC SULFUR COMPOUNDS
PRECURSOR
SPACE GROUPS
SYNTHESIS
X-RAY DIFFRACTION
CARBON COMPOUNDS
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
DATA
DATA FORMS
DIFFRACTION
DISTANCE
INFORMATION
MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
RADICALS
RESONANCE
SCATTERING
SPECTRA
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPLEXES
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400302 - Organic Chemistry- Isotope Effects- (-1987)