Charge transfer excitation of trivalent rare earth ions Sm/sup 3+/, Eu/sup 3+/, Gd/sup 3+/, Ho/sup 3+/, Er/sup 3+/ and Yb/sup 3+/ emission in BaFCl crystals
Journal Article
·
· Mater. Res. Bull.; (United States)
The charge transfer type excitation spectra of trivalent rare earth ions Sm/sup 3+/, Eu/sup 3+/, Gd/sup 3+/, Ho/sup 3+/, Er/sup 3+/ and Yb/sup 3+/ emission in BaFCl crystals have been studied. The charge transfer type emissions of Ho/sup 3+/, Er/sup 3+/ and Yb/sup 3+/ in BaFCl have also been observed in addition to that of Eu/sup 3+/. The energy of charge transfer band of these RE/sup 3+/ ions were estimated experimentally and also calculated by Jorgensen's refined electron spin-pairing energy theory. Both the experimental and calculated values coincide well.
- Research Organization:
- Dept. of Chemistry, Peking Univ., Beijing 100871
- OSTI ID:
- 6477176
- Journal Information:
- Mater. Res. Bull.; (United States), Vol. 22:1
- Country of Publication:
- United States
- Language:
- English
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+1 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BARIUM CHLORIDES
CHARGE TRANSPORT
EMISSION SPECTRA
BARIUM FLUORIDES
ERBIUM COMPOUNDS
EUROPIUM COMPOUNDS
GADOLINIUM COMPOUNDS
HOLMIUM COMPOUNDS
SAMARIUM COMPOUNDS
YTTERBIUM COMPOUNDS
CALCULATION METHODS
CRYSTALS
DATA ANALYSIS
ELECTRONS
EXCITATION
SPIN
ALKALINE EARTH METAL COMPOUNDS
ANGULAR MOMENTUM
BARIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
ELEMENTARY PARTICLES
ENERGY-LEVEL TRANSITIONS
FERMIONS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
LEPTONS
PARTICLE PROPERTIES
RARE EARTH COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties
400102 - Chemical & Spectral Procedures
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BARIUM CHLORIDES
CHARGE TRANSPORT
EMISSION SPECTRA
BARIUM FLUORIDES
ERBIUM COMPOUNDS
EUROPIUM COMPOUNDS
GADOLINIUM COMPOUNDS
HOLMIUM COMPOUNDS
SAMARIUM COMPOUNDS
YTTERBIUM COMPOUNDS
CALCULATION METHODS
CRYSTALS
DATA ANALYSIS
ELECTRONS
EXCITATION
SPIN
ALKALINE EARTH METAL COMPOUNDS
ANGULAR MOMENTUM
BARIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
ELEMENTARY PARTICLES
ENERGY-LEVEL TRANSITIONS
FERMIONS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
LEPTONS
PARTICLE PROPERTIES
RARE EARTH COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties
400102 - Chemical & Spectral Procedures