Novel anionic phosphine transition metal hydride complexes and their application to the catalytic hydrogenation of polar organic compounds
Conference
·
· Am. Chem. Soc., Div. Pet. Chem., Prepr.; (United States)
OSTI ID:6419743
Potassium tris(triphenylphosphine) ruthenium hydride complexed with diethyl ether and naphthalene was an effective homogeneous catalyst in the hydrogenation, under mild conditions (85/sup 0/-90/sup 0/C and 620 kPa hydrogen), of acetone to isopropanol, propanol to n-propanol, acrolein to allyl alcohol (and propionaldehyde), activated carboxylic acid esters, e.g., methyl trifluoroacetate and dimethyl oxalate, to corresponding alcohols, and acetonitrile to ethylamine. In most reactions, the selectivity for the hydrogenated products was above 90 per cent.
- Research Organization:
- Allied Chem. Corp.
- OSTI ID:
- 6419743
- Report Number(s):
- CONF-800303-
- Journal Information:
- Am. Chem. Soc., Div. Pet. Chem., Prepr.; (United States), Vol. 25:2; Conference: 179. national meeting of the American Chemical Society, Houston, TX, USA, 23 Mar 1980
- Country of Publication:
- United States
- Language:
- English
Similar Records
Oxidation, reduction, and isomerization of allyl alcohol and 1-propanol over Cu[sub 2]O(100)
Oxidation of propanol and isopropanol over silver catalyst. [220-320/sup 0/C]
Reactivity of MH([eta][sup 2]-H[sub 2]BH[sub 2])(CO)(PiPr[sub 3])[sub 2] (M = Os, Ru) toward electrophiles: Synthesis of new hydridocarbonylosmium(II) and -ruthenium(II) complexes containing triisopropylphosphine as ligand
Journal Article
·
Thu Jan 21 00:00:00 EST 1993
· Journal of Physical Chemistry; (United States)
·
OSTI ID:6419743
Oxidation of propanol and isopropanol over silver catalyst. [220-320/sup 0/C]
Journal Article
·
Thu Jan 01 00:00:00 EST 1976
· Kinet. Catal. (USSR) (Engl. Transl.); (United States)
·
OSTI ID:6419743
Reactivity of MH([eta][sup 2]-H[sub 2]BH[sub 2])(CO)(PiPr[sub 3])[sub 2] (M = Os, Ru) toward electrophiles: Synthesis of new hydridocarbonylosmium(II) and -ruthenium(II) complexes containing triisopropylphosphine as ligand
Journal Article
·
Wed Dec 23 00:00:00 EST 1992
· Inorganic Chemistry; (United States)
·
OSTI ID:6419743
+5 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANIC COMPOUNDS
HYDROGENATION
POLAR COMPOUNDS
RUTHENIUM COMPLEXES
CATALYTIC EFFECTS
CATALYSTS
ETHYL ETHER
NAPHTHALENE
POTASSIUM COMPOUNDS
RUTHENIUM HYDRIDES
ALKALI METAL COMPOUNDS
AROMATICS
CHEMICAL REACTIONS
COMPLEXES
CONDENSED AROMATICS
ETHERS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
RUTHENIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANIC COMPOUNDS
HYDROGENATION
POLAR COMPOUNDS
RUTHENIUM COMPLEXES
CATALYTIC EFFECTS
CATALYSTS
ETHYL ETHER
NAPHTHALENE
POTASSIUM COMPOUNDS
RUTHENIUM HYDRIDES
ALKALI METAL COMPOUNDS
AROMATICS
CHEMICAL REACTIONS
COMPLEXES
CONDENSED AROMATICS
ETHERS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
RUTHENIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties