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Title: The divorced eutectoid transformation in steel

Journal Article · · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science
 [1];  [2]
  1. Iowa State Univ., Ames, IA (United States). Materials Science and Engineering Dept.
  2. Ames Lab., IA (United States)

Experiments are presented which show that the eutectoid transformation in steel can occur by two different modes for temperatures just slightly below A{sub 1}. In the normal mode, the transformation product is lamellar pearlite. The second mode occurs if the austenite contains cementite particles or nuclei with a spacing on the order of a few microns or less. In this case, the transformation product consists of spheroidal cementite particles in a ferrite matrix. This second mode is here called the divorced eutectoid transformation (DET), after recent work by Sherby and co-workers. A literature survey shows that the faster kinetics of the DET over lamellar pearlite in the presence of inhomogeneous austenite was established before 1940, but has received little attention. The inhomogeneities are generally small cementite particles. Experiments show that the DET does not occur by a shell of one phase (ferrite) forming around the other phase of the eutectoid (cementite), as is the case in divorced eutectic growth. Rather, a fairly planar austenite/ferrite front simply advances into the austenite, with no apparent effect on its shape being produced by the cementite particles. A first-order kinetic model is presented for the growth velocity as a function of undercooling below A{sub 1} and is compared to the velocity vs undercooling for lamellar pearlite. The simple model indicates that the velocity of the divorced mode should be faster than the lamellar mode at low undercooling for cementite nuclei distributed in the austenite with spacings less than a few microns. This result is consistent with the experimental data.

Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
616494
Journal Information:
Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, Vol. 29, Issue 4; Other Information: PBD: Apr 1998
Country of Publication:
United States
Language:
English

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