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Title: Test plan for long-term, low-temperature oxidation of spent fuel, Series 1

Technical Report ·
OSTI ID:59922

Preliminary studies indicated the need for more spent fuel oxidation data in order to determine the probable behavior of spent fuel in a tuff repository. Long-term, low-temperature testing was recommended in a comprehensive technical approach to: (1) confirm the findings of the short-term thermogravimetric analyses scoping experiments; (2) evaluate the effects of variables such as burnup, atmospheric moisture and fuel type on the oxidation rate; and (3) extend the oxidation data base ot representative repository temperatures and better define the temperature dependence of the operative oxidation mechanisms. This document presents the Series 1 test plan to study, on a large number of samples, the effects of atmospheric moisture and temperature on oxidation rate and phase formation. Tests will run for up to two years, use characterized fragmented, and pulverized fuel samples, cover a temperature range of 110{sup 0}C to 175{sup 0}C and be conducted with an atmospheric moisture content rangeing from <-55{sup 0}C to {similar_to}80{sup 0}C dew point. After testing, the samples will be examined and made available for leaching testing.

Research Organization:
Hanford Engineering Development Lab., Richland, WA (United States)
DOE Contract Number:
AC06-76FF02170
OSTI ID:
59922
Report Number(s):
HEDL-7560; ON: DE86014756
Resource Relation:
Other Information: PBD: Jun 1986
Country of Publication:
United States
Language:
English