Synthesis and characterization of bis(. mu. -hydroxo)tetraaquadiplutonium(IV) sulfate, Pu/sub 2/(OH)/sub 2/(SO/sub 4/)/sub 3/. 4H/sub 2/O, a novel compound containing hydrolyzed plutonium (IV)
Journal Article
·
· Inorg. Chem.; (United States)
Pu/sub 2/(OH)/sub 2/(SO/sub 4/)/sub 3/.4H/sub 2/O(I) has been synthesized by hydrothermal hydrolysis of plutonium(IV) sulfate solution. I forms as reddish orange crystals at 140 +/- 5 /sup 0/C. Analytical data for Pu(coulometric), SO/sub 4//sup 2/-(gravimetric), and H/sub 2/O(thermogravimetric) are in agreement with theoretical values. X-ray powder diffraction data establish the isomorphicity of I with the Zr, Hf, and Ce analogues. Infrared spectra of I contain the peaks expected for hydroxo, aquo, and sulfato groups. Visible spectra of I are comparable to those for hydrated plutonium(IV) sulfate. Near-infrared spectra of I are reported. Comparisons between tetravalent hydroxsulfate compounds are made.
- Research Organization:
- Argonne National Lab., IL
- DOE Contract Number:
- W-31-109-ENG-38
- OSTI ID:
- 5991672
- Journal Information:
- Inorg. Chem.; (United States), Vol. 21:9
- Country of Publication:
- United States
- Language:
- English
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+1 more
Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLUTONIUM SULFATES
CHEMICAL PREPARATION
HYDROLYSIS
HYDRATES
HYDROGEN
OXYGEN
SPECTRA
THERMAL GRAVIMETRIC ANALYSIS
ACTINIDE COMPOUNDS
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
DECOMPOSITION
ELEMENTS
GRAVIMETRIC ANALYSIS
LYSIS
NONMETALS
OXYGEN COMPOUNDS
PLUTONIUM COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
SOLVOLYSIS
SULFATES
SULFUR COMPOUNDS
SYNTHESIS
THERMAL ANALYSIS
TRANSURANIUM COMPOUNDS
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
400201 - Chemical & Physicochemical Properties
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLUTONIUM SULFATES
CHEMICAL PREPARATION
HYDROLYSIS
HYDRATES
HYDROGEN
OXYGEN
SPECTRA
THERMAL GRAVIMETRIC ANALYSIS
ACTINIDE COMPOUNDS
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
DECOMPOSITION
ELEMENTS
GRAVIMETRIC ANALYSIS
LYSIS
NONMETALS
OXYGEN COMPOUNDS
PLUTONIUM COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
SOLVOLYSIS
SULFATES
SULFUR COMPOUNDS
SYNTHESIS
THERMAL ANALYSIS
TRANSURANIUM COMPOUNDS
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
400201 - Chemical & Physicochemical Properties