Characterization of carbonaceous soots by field ionization mass spectrometry: In search of C sub 60 and other fullerenes
Journal Article
·
· Journal of Physical Chemistry; (United States)
- SRI International, Menlo Park, CA (United States)
Characterization of several carbonaceous soots from pyrolysis and combustion processes by field ionization mass spectrometry shows the absence of peaks at 720 and 840 Da corresponding to C{sub 60} and C{sub 70} fullerenes. This absence coupled with the fact that these peaks are clearly seen in the soot obtained by vaporizing graphite in {approximately}150 Torr of He leads to the conclusion that the commonly encountered pyrolysis and combustion soots do not contain significant (larger than 0.1%) amounts of fullerenes.
- OSTI ID:
- 5953751
- Journal Information:
- Journal of Physical Chemistry; (United States), Vol. 95:12; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
SOOT
CHEMICAL COMPOSITION
CARBON COMPOUNDS
COMBUSTION
COMPARATIVE EVALUATIONS
CONDENSED AROMATICS
ELECTRIC FIELDS
EXPERIMENTAL DATA
HYDROCARBONS
IONIZATION
MASS SPECTROSCOPY
MOLECULAR WEIGHT
PYROLYSIS
AROMATICS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
EVALUATION
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
SPECTROSCOPY
THERMOCHEMICAL PROCESSES
400201* - Chemical & Physicochemical Properties
400800 - Combustion
Pyrolysis
& High-Temperature Chemistry
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
SOOT
CHEMICAL COMPOSITION
CARBON COMPOUNDS
COMBUSTION
COMPARATIVE EVALUATIONS
CONDENSED AROMATICS
ELECTRIC FIELDS
EXPERIMENTAL DATA
HYDROCARBONS
IONIZATION
MASS SPECTROSCOPY
MOLECULAR WEIGHT
PYROLYSIS
AROMATICS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
EVALUATION
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
SPECTROSCOPY
THERMOCHEMICAL PROCESSES
400201* - Chemical & Physicochemical Properties
400800 - Combustion
Pyrolysis
& High-Temperature Chemistry