Interaction of poly(pyridine)ruthenium(II) optical antipodes intercalated in montmorillonite clay
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The authors report here the UV-vis absorption spectra of (-)-RuL/sub 3//sup 2 +/ (L = 2,2'-bipyridine; 1,10-phenanthroline), (+)-RuL/sub 3//sup 2 +/, and (+/-)-RuL/sub 3//sup 2 +/ adsorbed on montmorillonite clay. The results provide compelling evidence of selective interactions between the optical antipodes of RuL/sub 3//sup 2 +/, when as few as 2-4% of the available cation exchange sites in clay are loaded with the Ru(II) complex.
- Research Organization:
- Alchemie Research Centre, Maharashtra, India
- OSTI ID:
- 5658889
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 108:15
- Country of Publication:
- United States
- Language:
- English
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· Inorg. Chem.; (United States)
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Bell-shaped energy-gap dependence of backward electron transfer occurring within geminate radical pairs produced by quenching of ruthenium(II) polypyridine complexes by aromatic amines
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·
OSTI ID:5658889
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
ABSORPTION SPECTROSCOPY
ENANTIOMORPHS
PHENANTHROLINES
RUTHENIUM COMPLEXES
ADDUCTS
CATIONS
EXPERIMENTAL DATA
MEDIUM TEMPERATURE
MONTMORILLONITE
SEPARATION PROCESSES
ULTRAVIOLET SPECTRA
VISIBLE SPECTRA
AROMATICS
AZAARENES
AZINES
CHARGED PARTICLES
CLAYS
COMPLEXES
DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
IONS
MATERIALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400105 - Separation Procedures
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
ABSORPTION SPECTROSCOPY
ENANTIOMORPHS
PHENANTHROLINES
RUTHENIUM COMPLEXES
ADDUCTS
CATIONS
EXPERIMENTAL DATA
MEDIUM TEMPERATURE
MONTMORILLONITE
SEPARATION PROCESSES
ULTRAVIOLET SPECTRA
VISIBLE SPECTRA
AROMATICS
AZAARENES
AZINES
CHARGED PARTICLES
CLAYS
COMPLEXES
DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
IONS
MATERIALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400105 - Separation Procedures