Studies relevant to the catalytic activation of carbon monoxide

Technical Report · Fri May 11 00:00:00 EDT 1990

OSTI ID:5552754

Ford, P C

Research activity during the current funding period (December 87 to present) of this grant has included continued mechanistic investigations of the nucleophilic activation of carbon monoxide such as homogeneous catalysis of the water gas shift and key steps in the relevant catalytic cycles. In addition, new investigations of related processes involved in the catalytic activation of carbon monoxide and other C{sub 1} compounds were initiated. These include the application of fast reaction techniques to prepare and to investigate quantitatively reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and other functionalizations. 39 refs., 7 figs.

• Research Organization: California Univ., Santa Barbara, CA (USA). Dept. of Chemistry
• Sponsoring Organization: USDOE; USDOE, Washington, DC (USA)
• DOE Contract Number: FG03-85ER13317
• OSTI ID: 5552754
• Report Number(s): DOE/ER/13317-T1; ON: DE91012661
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
CHEMICAL ACTIVATION
CARBONYLATION
REACTION KINETICS
CATALYSTS
MOLECULAR STRUCTURE
REACTION INTERMEDIATES
QUANTITATIVE CHEMICAL ANALYSIS
RUTHENIUM COMPLEXES
CATALYTIC EFFECTS
SHIFT PROCESSES
CARBON 13
CARBONYLS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN PRODUCTION
IRIDIUM COMPLEXES
ORGANOMETALLIC COMPOUNDS
PHOTOCHEMISTRY
PHOTOLYSIS
PROGRESS REPORT
RHODIUM COMPLEXES
CARBON COMPOUNDS
CARBON ISOTOPES
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DECOMPOSITION
DOCUMENT TYPES
EVEN-ODD NUCLEI
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties