Reactions of 2-chloro-1-alkanimines with trialkyl phosphites and with triphenylphosphine

Journal Article · Sat Sep 20 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5324733

Sinitsa, A D; Krishtal', V S; Momot, V V; Maidanovich, N K; Kal'chenko, V I

The reactivity of 2-chloro-1-alkanimines toward trialkyl phosphites and triphenylphosphine is determined by the electronic properties of the substituents in the azomethine group. Donor substituents direct the reaction toward the formation of C-phosphorylation products. The introduction of electron-acceptor substituents on the nitrogen and carbon atoms of the azomethine group raises its reactivity considerably toward nucleophilic phosphorus(III) compounds and leads to products with a nitrogen-phosphorus bond. Phosphorus 31 NMR and chlorine 35 NQR spectra are analyzed.

• Research Organization: Institute of Organic Chemistry, Kiev (USSR)
• OSTI ID: 5324733
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 56:4; Other Information: Translated from Zh. Obshch. Khim.; 56: No. 4, 805-809(Apr 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
CHLORINATED ALIPHATIC HYDROCARBONS
ACTIVATION ENERGY
PHOSPHORYLATION
IMINES
ORGANIC PHOSPHORUS COMPOUNDS
NMR SPECTRA
AZO COMPOUNDS
BINDING ENERGY
CHEMICAL REACTION KINETICS
CHEMICAL SHIFT
CHLORINE 35
COUPLING CONSTANTS
J-J COUPLING
MULTIPLETS
NUCLEAR QUADRUPOLE RESONANCE
PHOSPHORUS 31
SYNTHESIS
CHEMICAL REACTIONS
CHLORINE ISOTOPES
COUPLING
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
INTERMEDIATE COUPLING
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOSPHORUS ISOTOPES
REACTION KINETICS
RESONANCE
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory