Assessment of adsorption/solvent extraction with polyurethane foam and adsorption/thermal desorption with Tenax-GC for the collection and analysis of ambient organic vapors
Two methods for the collection of ambient organic vapors at the ng/m/sup 3/ to ..mu..g/m/sup 3/ level were utilized in field sampling at a residential site in Portland, OR, during the winter and spring of 1983. The methods were adsorption/solvent extraction with polyurethane foam plugs (ASE/PUFP) and adsorption/thermal desorption with Tenax-GC cartridges (ATD/Tenax-GC). ASE/PUFP was used with a single sample flow rate in a single channel of the sampler. ATD/Tenax-GC was used with two different sample flow rates in two separate channels. Each method was found to be well suited to the analysis of compounds in a specific range of volatility. Some intermediate-volatility compounds were determined with all three sampling channels. The coefficients of variation for the three channels pooled over seven events were 9-36% for compounds in the range of volatility between acenaphthene and pyrene. The low sample volumes used with ATD/Tenax-GC for determinations at the ng/m/sup 3/ level make it an attractive method for many applications.
- Research Organization:
- Oregon Graduate Center, Beaverton
- OSTI ID:
- 5274549
- Journal Information:
- Anal. Chem.; (United States), Vol. 57:6
- Country of Publication:
- United States
- Language:
- English
Similar Records
Adsorption/thermal desorption with small cartridges for the determination of trace aqueous semivolatile organic compounds
Trace organic compounds in rain. 1. Sampler design and analysis by adsortion/thermal desorption (ATD)
Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
AIR
QUANTITATIVE CHEMICAL ANALYSIS
AIR SAMPLERS
PERFORMANCE
CHLORINATED AROMATIC HYDROCARBONS
ADSORPTION
DESORPTION
SOLVENT EXTRACTION
POLYCYCLIC AROMATIC HYDROCARBONS
POLYURETHANES
SORPTIVE PROPERTIES
VAPORS
EXPERIMENTAL DATA
TRACE AMOUNTS
AROMATICS
CHEMICAL ANALYSIS
DATA
EQUIPMENT
EXTRACTION
FLUIDS
GASES
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
MATERIALS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
POLYAMIDES
POLYMERS
SAMPLERS
SEPARATION PROCESSES
SORPTION
SURFACE PROPERTIES
SYNTHETIC MATERIALS
400102* - Chemical & Spectral Procedures
500200 - Environment
Atmospheric- Chemicals Monitoring & Transport- (-1989)