Leaching behavior of EDTA in a silica sol-gel matrix

Book · Sat Dec 31 00:00:00 EST 1994

OSTI ID:51581

Oka, K S; Mackenzie, J D ^[1]

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1. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering

Ethylene diamine tetra-acetic acid (EDTA) doped silica gels were made by the sol-gel process for the potential application as a filter for heavy metal ions in wastewater. The behavior of the organic molecule in the matrix was studied by investigating the percentage of EDTA leached out with a variation in the timing of addition of the EDTA molecule into the starting silica gel solution. Leach tests using water as the medium were performed for 2, 12 and 24 hours in order to determine the amount of EDTA trapped in the pores or in the matrix. A minimum amount of EDTA leached from the gels was detected in the samples to which EDTA was added 4 hours after initial hydrolysis of TEOS. This result was correlated to having a greater percentage of pore volume in the range of 15--20 {angstrom}, which was further substantiated with density measurements. The physical changes in the silica matrix altering the pore volume distribution were attributed to the addition of the water into which the EDTA molecule was initially dissolved.

• OSTI ID: 51581
• Report Number(s): CONF-940411-; ISBN 1-55899-246-4; TRN: IM9524%%46
• Resource Relation: Conference: Spring meeting of the Materials Research Society (MRS), San Francisco, CA (United States), 4-8 Apr 1994; Other Information: PBD: 1994; Related Information: Is Part Of Better ceramics through chemistry VI. Materials Research Society symposium proceedings Volume 346; Cheetham, A.K. [ed.] [Univ. of California, Santa Barbara, CA (United States)]; Brinker, C.J. [ed.] [Sandia National Labs., Albuquerque, NM (United States)]; Mecartney, M.L. [ed.] [Univ of California, Irvine, CA (United States)]; Sanchez, C. [ed.] [Univ. Pierre et Marie Curie, Paris (France)]; PB: 1069 p.
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
COMPOSITE MATERIALS
CHEMICAL PREPARATION
SILICA GEL
PHYSICAL PROPERTIES
EDTA
LEACHING
WATER TREATMENT PLANTS
GRANULAR BED FILTERS
WATER
DOPED MATERIALS
FLOWSHEETS
FOURIER TRANSFORM SPECTROMETERS
MOLECULAR STRUCTURE
POROSITY
BULK DENSITY
EXPERIMENTAL DATA