Porphyrins. 21. Synthesis and reactivities of 13,17-disubstituted derivatives of 13,17-desethyletioporphyrin III
Journal Article
·
· Chem. Heterocycl. Compd. (Engl. Transl.); (United States)
A method was developed for the preparation, from hemin, of a porphyrin with hydroxypropyl substituents in the 13 and 17 positions of the macroring and a number of its derivatives. The UV and visible spectra of solutions of the compounds in chloroform were recorded with an SF-18 spectrophotometer. The IR spectra of KBr pellets of the compounds were obtained with a Perkin-Elmer 398 spectrometer. The PMR spectra of solutions in CDCl/sub 3/ (with the addition of 5% d/sub 5/-pyridine in the case of the zinc complexes) were recorded with Bruker WM-360 and WM-250 spectrometers with tetramethylsilane (TMS) as the internal standard. The mass spectra were recorded with a Varian MAT-311 spectrometer.
- Research Organization:
- Institute of Biophysics, Moscow (USSR)
- OSTI ID:
- 5099460
- Journal Information:
- Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Vol. 23:2; Other Information: Translated from Khim. Geterotsikl. Soedin.; 23: No. 2, 214-220(Feb 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PORPHYRINS
ACTIVATION ENERGY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
ALUMINIUM HYDRIDES
BOROHYDRIDES
CATALYTIC EFFECTS
CHEMICAL SHIFT
CHLOROFORM
DEUTERIUM COMPOUNDS
INFRARED SPECTRA
ISOTOPE EFFECTS
LITHIUM HYDRIDES
MASS SPECTRA
NMR SPECTRA
ULTRAVIOLET SPECTRA
ZINC COMPLEXES
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
BORON COMPOUNDS
CARBOXYLIC ACIDS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPLEXES
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
LITHIUM COMPOUNDS
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PORPHYRINS
ACTIVATION ENERGY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
ALUMINIUM HYDRIDES
BOROHYDRIDES
CATALYTIC EFFECTS
CHEMICAL SHIFT
CHLOROFORM
DEUTERIUM COMPOUNDS
INFRARED SPECTRA
ISOTOPE EFFECTS
LITHIUM HYDRIDES
MASS SPECTRA
NMR SPECTRA
ULTRAVIOLET SPECTRA
ZINC COMPLEXES
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
BORON COMPOUNDS
CARBOXYLIC ACIDS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPLEXES
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
LITHIUM COMPOUNDS
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties