Investigation of the oxidation of carbon disulfide in gas flows using IR spectroscopy

Journal Article · Wed May 01 00:00:00 EDT 1985

OSTI ID:5038355

Dudkin, V A; Ogurechnikov, V A; Rukhin, V B

The oxidation of carbon disulfide has been intensively studied recently because the carbon monoxide molecules formed during the chemical reaction have a large amount of vibrational energy and can be used to create laser media. Previously, studies have been made of the IR emission from a carbon disulfide flame and the dependence of the intensoty of emission from CO and CO/sub 2/ molecules on the stoichiometric ratio between the oxide and fuel concentrations has been found. In this paper the authors present the results from a spectroscopic study of the emission from a flame in the near infrared. The purpose of this work is to compare the spectra of carbon disulfide flames in different mixtures as well as to find the dependence of their shape on the pressure of the medium for a more detailed study of the effect of chemical and vibrational kinetics on the emission from CO molecules.

• OSTI ID: 5038355
• Resource Relation: Journal Volume: 20:6; Other Information: Translated from Fizika Goreniya i Vzryva. Vol. 20, No. 6, pp. 109-114, November-December, 1984
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON SULFIDES
INFRARED SPECTRA
CARBON DIOXIDE
CARBON MONOXIDE
COMBUSTION KINETICS
EMISSION SPECTROSCOPY
FLAMES
GAS FLOW
OXIDATION
PRESSURE DEPENDENCE
SHAPE
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
FLUID FLOW
KINETICS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
SPECTRA
SPECTROSCOPY
SULFIDES
SULFUR COMPOUNDS
400800* - Combustion
Pyrolysis
& High-Temperature Chemistry