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Title: Development of a scalable Tl-1223 tape process -- thallination of powder precursor coatings

Journal Article · · Advances in Cryogenic Engineering
OSTI ID:483598
;  [1];  [2]
  1. GE Corporate Research & Development, Schenectady, NY (United States)
  2. National Renewable Energy Lab., Golden, CO (United States); and others

Superconducting tapes, 10-20 cm long, of TlBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub 9} on Ag have been fabricated by deposition of a thallium-free powder precursor on Ag followed by reaction with a thallium oxide vapor species. Single-sided and two-sided coatings are prepared using a spray-deposition or dip-coating, respectively. The coated tapes are annealed and then mechanically processed to densify the precursor. Continuous thallination of precursor tapes is performed by pulling the coated tape through a two-zone furnace at constant velocity and gave similar results as batch processing. Critical currents of the order 10-20 A at 77K, zero field for a 5 mm wide tape are observed. Properties as a function of magnetic field indicate reduced flux creep compared to the more anisotropic bismuth cuprate superconductors and make thallium 1223 an attractive material for conductor applications at high temperatures.

DOE Contract Number:
AC05-84OR21400
OSTI ID:
483598
Report Number(s):
CONF-950722-; ISSN 0065-2482; TRN: 97:001732-0049
Journal Information:
Advances in Cryogenic Engineering, Vol. 42B; Conference: CEC/ICMC `95: cryogenic engineering conference and international cryogenic materials conference, Columbus, OH (United States), 17-21 Jul 1995; Other Information: PBD: 1997
Country of Publication:
United States
Language:
English