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Title: Bioremediation of RDX in the vadose zone beneath the Pantex Plant

Technical Report ·
DOI:https://doi.org/10.2172/307838· OSTI ID:307838
; ;  [1]
  1. Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering

The presence of dissolved high explosives (HE), in particular RDX and HMX, is well documented in the perched aquifer beneath the Pantex Plant, but the distribution of HE in the vadose zone has not yet been well defined. Although current remediation activities focus on the contamination in the perched aquifer, eventually regulatory concern is likely to turn to the residual contamination in the vadose zone. Sources of HE include the infiltration of past wastewater discharges from several HE-processing facilities through the ditch drainage system and leachate from former Landfill 3. With limited existing data on the HE distribution in the vadose zone and without preventive action, it must be assumed that residual HE could be leached into infiltrating water, providing a continuing supply of contamination to the perched aquifer. The purpose of this project was to more closely examine the fate and transport of HE in the vadose zone through mathematical modeling and laboratory experimentation. In particular, this report focuses on biodegradation as one possible fate of HE. Biodegradation of RDX in the vadose zone was studied because it is both present in highest concentration and is likely to be of the greatest regulatory concern. This study had several objectives: determine if indigenous soil organisms are capable of RDX biodegradation; determine the impact of electron acceptor availability and nutrient addition on RDX biodegradation; determine the extent of RDX mineralization (i.e., conversion to inorganic carbon) during biodegradation; and estimate the kinetics of RDX biodegradation to provide information for mathematical modeling of fate and transport.

Research Organization:
Amarillo National Resource Center for Plutonium, TX (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
FC04-95AL85832
OSTI ID:
307838
Report Number(s):
ANRCP-1999-1; ON: DE99001565; TRN: AHC29905%%15
Resource Relation:
Other Information: PBD: Jan 1999
Country of Publication:
United States
Language:
English