The Applications of Intumescent Technologies in Support of D and D Activities across the DOE Complex - 19599
- Applied Research Center - FIU (United States)
- Savannah River National Laboratory (United States)
The development of intumescent technologies to be used as both an excellent means of fire protection and resiliency and as a radioactive fixative, would most definitely benefit the safety of the general public and also the environment. The remediation and safe disposal of radioactive waste is of great important to both national security and the public health, as we carry the responsibility to not develop new ways of mitigating these hazards but also to lay the groundwork for future generations. The overall goal of this research is to enhance the fire resiliency and protection of fixatives and nuclear facilities in support of D and D activities. Specific objectives include: 1) identify and evaluate commercial-off-the-shelf (COTS) intumescent technologies, 2) conduct baseline fire testing of intumescent technologies, 3) develop a set of international standards to meet operational and safety requirements for D and D Technologies. In order to evaluate the above proposed research objectives, the following hypotheses have been postulated. - Select, test, and evaluate the suitability of certain 'near fit' ASTM flammability standards. - Baseline and down-select a set of existing COTS intumescent technologies (coatings and foams) to support D and D problem sets. - Determine feasibility of application methods for use inside a radioactive glovebox and hot cells for D and D purposes. - Develop international testing protocols for adapting the use of intumescent technologies to address needs of the D and D process. The proposed research will primarily take place at FIU-ARC. ARC and SRNL have conducted extensive coordination with the Savannah River Site's (SRS) 235-F PuFF facility personnel to facilitate planning in order to expedite the research and development (R and D) related to this effort. An initial set of documents associated with the specific facility hot cells, including schematics, assessment of the manipulator arms, anticipated particulate sizes of the Pu-238 contamination, an approved tooling list, etc., were formally reviewed and approved for release by the site to ARC. Utilizing these as a foundation, pre-planning for further adaptation of the intumescent technologies and the application during a full-scale cold demo at a hot cell testbed at ARC. One of the primary objectives is the testing and evaluation of the resistance of radiological shielding foams to thermal stressors. This objective was accomplished by conducting a flammability test and incremental temperature test. The goal of the flammability test is to conduct analytical tests to provide a classification for the foams as outlined below in accordance with IEC 60695-11-10. This test method is uniformly accepted throughout the industry as being critical indicators that quantifiably establish the flammability characteristics of plastics. It should be noted that polyurethane is not classified as a plastic, however, they do share similar properties deeming this a near fit test. IEC 60695-11-10:2013 specifies small-scale laboratory test procedures intended to compare the burning behavior of different materials when vertically or horizontally oriented test bar specimens are exposed to a small flame ignition source. Two test methods are described. Method A is a horizontal burning test and is intended to determine the linear burning rate of materials under specific test conditions. Method B is a vertical burning test and is intended to determine whether materials self-extinguish under specific test conditions. The purpose of the incremental temperature testing is to evaluate mass loss and dimensional changes that occurs to the radiological shielding foams when exposed to high temperatures in a muffle furnace. High temperatures often cause materials to undergo physical changes such as swelling or expanding. This is caused by the increase in kinetic energy and atomic and molecular movement.
- Research Organization:
- WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (United States)
- OSTI ID:
- 23005445
- Report Number(s):
- INIS-US-21-WM-19599; TRN: US21V1372045779
- Resource Relation:
- Conference: WM2019: 45. Annual Waste Management Conference, Phoenix, AZ (United States), 3-7 Mar 2019; Other Information: Country of input: France; 12 refs.; available online at: https://www.xcdsystem.com/wmsym/2019/index.html
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
CLASSIFICATION
COATINGS
FLAMMABILITY
FOAMS
GLOVEBOXES
HOT CELLS
KINETIC ENERGY
MANIPULATORS
MASS TRANSFER
NUCLEAR FACILITIES
OCCUPATIONAL SAFETY
PLUTONIUM 238
POLYURETHANES
RADIATION HAZARDS
RADIATION PROTECTION
RADIOACTIVE WASTES
REMEDIAL ACTION
SAVANNAH RIVER PLANT
SHIELDING
SURFACE CONTAMINATION
SWELLING
TESTING