Applications of Transient Grating Spectroscopy to Radiation Materials Science
- MIT Nuclear Science and Engineering, 77 Massachusetts Ave., Room 24-204, Cambridge,MA, 02139 (United States)
- Mech. and Bio. Engineering, City University of Hong Kong, 83 Tat Chee Ave, Kowloon Tong (Hong Kong)
Radiation damage is an inherently multi-scale phenomenon, with much of the key material evolution occurring at the mesoscale. Current techniques for the direct interrogation of material property changes due to irradiation either function with very small volumes, such as in-situ TEM, cannot cover the full range of defect populations produced, such as in positron annihilation spectroscopy, or requires destruction of the test material, such as in standard or micromechanical testing. In addition, the ultimate quantities of interest to radiation materials scientists are the changes in key material properties with irradiation. These include stiffness, ductility, and thermal conductivity for structural materials, and optical properties such as index of refraction or changes in transmittance spectra for optically active materials. The latter of these are often correlated directly to stress- or thermally-induced changes, themselves a function of the specific defect populations responsible for their change. The rapid study of such a mesoscale phenomenon requires an inherently mesoscale technique, where multiple quantities of interest can be accurately measured in very short times. Determining the sensitivity of any technique with known certainly is of critical importance to qualifying a new technique to measure in-situ material property changes during irradiation. In this paper, we present the new applicability of an existing technique, known as transient grating (TG) spectroscopy, to rapidly and accurately study key problems in radiation materials science. Results quantifying the absolute sensitivity of the technique are presented, alongside molecular dynamics (MD) simulations of the TG spectroscopy process to gauge direct agreement between theory, simulation, and experiment. An example problem of interest is demonstrated as an illustration of what is possible, showing elastic and thermal changes in irradiated silicon carbide (SiC) films. Finally, future work to quantify the effects of experimentally-simulated radiation defects is proposed, in support of building a database to use TG spectroscopy to deconvolve irradiated material property changes in-situ in terms of the defect populations responsible for their evolution. The application of the TG spectroscopy technique to in-situ radiation materials science has the potential to answer long-standing questions in the field, relating to ion beam rastering, the onset of void swelling, and direct measurement of radiation-created point defect concentrations. Before it can do so, the technique must carefully be analyzed and tuned to increase its sensitivity, the certainty of its results, and the ability to predict radiation-induced changes by simulations must be developed. Making such measurements in-situ with the aid of predictive MD simulations has the potential to elucidate mechanisms of radiation damage accumulation, as well as more rapidly qualify radiation-resistant alloys for service in nuclear systems. Work is underway to build this database of experimentally-simulated radiation-produced defects, which will be combined and compared with actual irradiated materials for eventual in-situ deconvolution of the TG signal into the defect populations responsible for irradiation-induced microstructural change. (authors)
- OSTI ID:
- 22992075
- Journal Information:
- Transactions of the American Nuclear Society, Vol. 114, Issue 1; Conference: Annual Meeting of the American Nuclear Society. Embedded topical meeting 'Nuclear fuels and structural material for the next generation nuclear reactors', New Orleans, LA (United States), 12-16 Jun 2016; Other Information: Country of input: France; 16 refs.; Available from American Nuclear Society - ANS, 555 North Kensington Avenue, La Grange Park, IL 60526 United States; ISSN 0003-018X
- Country of Publication:
- United States
- Language:
- English
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36 MATERIALS SCIENCE
BUILDING MATERIALS
DEFECTS
DUCTILITY
FLEXIBILITY
ION BEAMS
IRRADIATION
MOLECULAR DYNAMICS METHOD
POINT DEFECTS
POSITRON ANNIHILATION SPECTROSCOPY
RADIATION EFFECTS
REFRACTIVE INDEX
SENSITIVITY
SILICON CARBIDES
SIMULATION
THERMAL CONDUCTIVITY
TRANSMISSION ELECTRON MICROSCOPY